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iATERIAL SAFETY DATA SHL r RECEIVED <br /> VALERO <br /> OCT 21 2013 <br /> 1. Product and Company Identification ENVIRONMENTAL <br /> Material name DIESEL FUELS HEALTH DEPARTMENT <br /> Version# 03 <br /> Issue date 09-November-2010 <br /> Revision date 25-June-2013 <br /> Supersedes date 04-November-2012 <br /> MSDS Number 102 <br /> Product use Refinery feedstock. <br /> Synonym(s) Diesel Fuels All Grades, Diesel Fuel No.2, Fuel Oil No.2, High Sulfur Diesel Fuel, Low Sulfur <br /> Diesel Fuel, Ultra Low Sulfur Diesel Fuel, GARB(Califomia Air Resource Board)Diesel Fuel, <br /> Off-Road Diesel Fuel, Dyed Diesel Fuel,X Grade Diesel Fuel, X-1 Diesel Fuel, RS ULSD, B5 ULS <br /> D See section 16 for complete information. <br /> Man ufactu rerlS upplier Valero Marketing&Supply Company and Affiliates <br /> P.O. Box 696000 <br /> San Antonio,TX 78269-6000 <br /> General Assistance 210-345-4593 <br /> Emergency 24 Hour Emergency 866-565-5220 <br /> 1-800-424-9300(CHEMTREC USA) <br /> 2. Hazards Identification <br /> Physical state Liquid. <br /> Appearance Liquid(may be dyed red). <br /> Emergency overview WARNING! <br /> Combustible liquid and vapor.May be ignited by heat, sparks or flames. Heat may cause the <br /> containers to explode. <br /> Harmful if inhaled or swallowed. May be harmful if absorbed through skin.Aspiration may cause <br /> lung damage. Irritating to eyes, respiratory system and skin. In high concentrations,vapors and <br /> spray mists are narcotic and may cause headache,fatigue, dizziness and nausea. Suspect cancer <br /> hazard-may cause cancer. Prolonged exposure may cause chronic effects. Diesel exhaust has <br /> been reported to be an occupational hazard due to NIOSH-reported potential carcinogenic <br /> properties. Hydrogen sulfide,a highly toxic gas, may be present or released. Signs and symptoms <br /> of overexposure to hydrogen sulfide include respiratory and eye irritation, dizziness, nausea, <br /> coughing, a sensation of dryness and pain in the nose, and loss of consciousness. Odor does not <br /> provide a reliable indicator of the presence of hazardous levels in the atmosphere.Toxic to aquatic <br /> organisms. May cause long-term adverse effects in the aquatic environment.The toxicological <br /> properties of this material have not been fully investigated. <br /> Static accumulating flammable materials can become electrostatically charged even in bonded <br /> and grounded equipment. Sparks may ignite material and vapor may cause flash fire(or <br /> explosion). <br /> OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200(Hazard Communication). <br /> Potential health effects <br /> Routes of exposure Inhalation. Ingestion.Skin contact. Eye contact. <br /> Eyes Contact may irritate or burn eyes. Eye contact may result in corneal injury. <br /> Skin May be harmful if absorbed through skin. Irritating to skin. Frequent or prolonged contact may <br /> defat and dry the skin, leading to discomfort and dermatitis. <br /> Inhalation Harmful if inhaled. Irritating to respiratory system. In high concentrations,vapors and spray mists <br /> are narcotic and may cause headache,fatigue,dizziness and nausea.May cause breathing <br /> disorders and lung damage. May cause cancer by inhalation. Prolonged inhalation may be <br /> harmful. <br /> Ingestion Harmful if swallowed. Ingestion may result in vomiting; aspiration(breathing)of vomitus into lungs <br /> must be avoided as even small quantities may result in aspiration pneumonitis. Irritating to mouth, <br /> throat, and stomach. <br /> Target organs Blood. Eyes. Liver. Respiratory system. Skin. Kidneys. Central nervous system. <br /> DIESEL FUELS <br /> 3541 Version ik 03 Revison date:25-June-2013 Print date:25-June-2013 1 113 <br /> Prepared by 3E Company <br />