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Aug. 18. 2015 4: 01PM HAPPY BEE'S No. 2041 P. 11 -- PRWIR Praxair Safety Data Sheet RE�EIV�® MuMig nnrpla nl ubavpnkArrdm Product: Carbon Dioxide SAS No. P-4574-K March 2013 UG 18 2015 cylinder may cause rupture. Use a check valve or other protective device in any line or piEWRONMENTAL HEgL7H from the cylinder. Do not strike an are on the cylinder. The defect produced by an arc burn ZSERVICES Could lead to cylinder rupture. Do not ground the cylinder or allow It to became part of an electrical circuit. Firmly secure cylinders upright to keep therm from falling or being knocked over, Screw valve protection cap firmly in place by hand. Store full and empty cylinders separately. Use a first-in, first-out inventory system to prevent storing full cylinders for long periods. RECOMMENDED PUBLICATIONS: For further information on storage, handling,and use, see Praxalr publications P-14-153, Guidelines for Handling Gas Cylinders and Containers;P-15- 073, Safety Precautions for Carbon Dioxide;and P-3499, Safety Precautions and Emergency Response Planning. Obtain from your local supplier, S. 1=xposurs Controls/Personal Protection See section 16 for Important Information on by-products generated during use in welding and cutting, COMPONENT ]OSHA PEL �:JACGIH TLV (2012) Carbon dioxide 15,000 pom 16,000 ppm TWA, 30,000 ppm 15-min STEL IDLH=40,000 ppm, ENGINEERING CONTROLS: Local Exhaust. Use a local exhaust system, if necessary,to keep the concentration of carbon dioxide below all applicable exposure limits in the worker's breathing zone. Mechanical (General), Under certain conditions, general exhaust ventilation may be acceptable to keep carbon dioxide below the exposure limits. Special, WARNING: Concentration levels of carbon dioxide about 1 percent are dangerous--see Section 11, Praxalr recommends continuous monitoring with alarms to Indicate unsafe conditions before and during potential personnel exposure. Use appropriate monitoring devices to ensure a safe oxygen level (minimum of 19.5 percent)and a safe carbon dioxide level. Other. None PERSONAL PROTECTIVE EQUIPME=NT(PPE): Skin Protection. Wear insulated neoprene gloves for cylinder handling; welding gloves for welding, Metatarsal shoes for cylinder handling, Select In accordance with OSHA 29 CFR 1910,132, 1910.136, and 1910.138. See section 16 for requirements when using carbon dioxide or carbon dioxide mixtures In welding and cutting. Eye/Face Protection, Select in acmrdance with OSHA 29 CFR 1910,133. See section 16 for requirements when using carbon dioxide or carbon dioxide mixtures in welding and cutting. Respiratory Protection, None required under normal use. An air-supplied respirator must be used in confined spaces. Respiratory protection must conform to OSHA rules as specified in 29 CFR 1910.134. Select per OSHA 29 CFR 1910.134 and ANSI 288.2. Page 4 of 12