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r. i. <br />i a Shutt <br />IX SPECIAL PRECAUTIONS <br />PRECAUTIONARY STATEMENTS <br />DANGER! <br />Causes Severe Burns to Skin and Eyes <br />Do NOT get in eyes, on skin, on clothing. <br />Avoid breathing dust, mist, or spray. <br />Do NOT take internally. <br />Use with adequate ventilation and employ respiratory protection when exposed to dust, mist or spray. <br />When handling, wear chemical splash goggles, face shield, rubber gloves and protective clothing. <br />Wash thoroughly after handling. <br />Avoid contact with strong acids to prevent violent or explosive reactions. <br />Keep container closed. <br />Hazardous carbon monoxide gas can form upon contact with food and beverage products in enclosed spaces and can cause <br />death. Follow appropriate tank entry procedures (ANSI Z117.1-1977). <br />First Aid: <br />In czse of contact: <br />For eyes: Immediately flush with plenty of water for at least 15 minutes holding eyelids apart to ensure flushing of the entire <br />eye surface. Seek medical attention immediately. <br />Skin: immediately wash with plenty of water. If available, rinse with vinegar or dilute acetic acid (31; solution). Remove <br />contaminated clothing and footwear. Wash clothing before reuse and discard footwear which cannot be decontaminated. <br />Seek medical attention immediately. <br />Inhai=_tion: Remove person from contaminated area to fresh air. If breathing has stopped, artificial respiration should be <br />started. Oxygen may be administered if readily available. Seek medical attention immediately. <br />Ingestion: If swallowed, DO NOT induce vomiting. Give large quantities of water. If available, give several glasses of milk. <br />NEVER give anything by mouth to an unconscious person. Seek medical attention immediately. <br />instructions for dissolving ar; ydrC•Us caustic soda: <br />When making solution, always add slowly to liquid surface with constant stirring. Never add the liquid to the caustic soda <br />Always start with lukewarm liquid (80°-100°F.) Never start with hot or cold liquid. <br />If caustic soda becomes concentrated in one area, or if added too rapidly, or if added to hot or cold liquid, a rapid temperature <br />increase can result in DANGEROUS boiling and/or spattering which may cause an immediate VIOLENT ERUPTION. <br />Spill or Leak: Leaks should be stopped. Spills, after containment, should be shoveled up and removed to chemical waste area or <br />removed by vacuum truck, if liquid. Neutralize residue with dilute acid, flush spill area with water followed by liberal covering of <br />sodium bicarbonate. Dispose of wash water according to Federal. State and Local regulations. <br />For Industrial Use Only <br />OTHER HANDLING AND STORAGE REQUIREMENTS <br />Caustic soda is classified by D.O.T. as a corrosive material. <br />Considerable heat is generatedwhen water is added to caustic soda; therefore, when making solutions always add the caustic <br />soda to the water with constant stirring. The water should always be lukewarm (80°-100°F) Never start with hot or cold water. If <br />caustic soda becomes concentrated in one area, or if added too rapidly, or if added to hot or cold water, a rapid temperature <br />increase can result in DANGEROUS BOILING and/or spattering or may cause an immediate VIOLENT ERUPTION. Caustic <br />soda can react violently or explosively with acids and many organic chemicals. <br />Caustic soda reacts with reducing sugars such as fructose, lactose, maltose, galactose, levulose and arabinose to form carbon <br />monoxide. While the potential for worker exposure to carbon monoxide may be small, a potential does exist during cleaning of <br />certain dairy and possibly other industry equipment. <br />w <br />Returnable containers should be shipped in accordance with supplier's recommendations. Return shipments should comply <br />with all federal, state and DOT regulations. All residual caustic soda should be removed from containers prior to disposal. <br />More information on the hazards and handling of caustic soda appear in Diamond Shamrock Corporation's Caustic Soda <br />Handbook EC -LDC -1c. <br />DEPARTMENT OF TRANSPORTATION INFORMATION <br />PROPER SHIPPING NAME: Caustic Soda, Dry <br />HAZARD CLASS: Corrosive Material <br />PREPARED BY: Diamond Shamrock Corporation DATE: <br />Technical Service Group July 1, 1980 <br />