Laserfiche WebLink
Mr. James Barton <br />April 14, 2004 <br />Page 2 <br />PROPOSED SCOPE OF WORK <br />SECOR proposes injecting pre -mixed 30% potassium persulfate catalyst solution, then 10% <br />hydrogen peroxide solution at flow rates varying from 0.5 — 5 gallons per minute (GPM) over a period <br />of two days for a total of 840 gallons (380 pounds of hydrogen peroxide). The volume of hydrogen <br />peroxide injected was calculated to be 2 to 5 times the stoichiometric amount required to treat the <br />existing mass of contaminant still present on the site (greater than 1,000 micrograms per liter (ug/L)). <br />SITE HEALTH AND SAFETY PLAN <br />As required by the Occupational Health and Safety Administration (OSHA) Standard "Hazardous <br />Waste Operations and Emergency Response" guidelines (29 Code of Federal Regulations Section <br />1910.120), and by California Occupational Health and Safety Administration (Cal -OSHA) "Hazardous <br />Waste Operations and Emergency Response" guidelines (California Code of Regulations Title 8, <br />Section 5192), SECOR will prepare, or modify the existing, site-specific health and safety plan <br />(SHSP) prior to the commencement of fieldwork. Field staff and contractors will review the SHSP <br />before beginning field operations at the site. <br />EQUIPMENT AND SOLUTION PREPARATION <br />The drum transfer pump, well cap, totalizer and pressure relief valve internal parts will be made of <br />316 SS, PVC, PP or PE plastic materials, or similar materials compatible with applied chemicals at <br />concentrations less than 50% and temperatures less than 200 OF. Brass, lower grade steel or other <br />incompatible materials can corrode or weaken with chemical use causing leaks and operation failure. <br />10% Hydrogen Peroxide Solution Mixing <br />A solution will be mixed using 50% hydrogen peroxide, slowly added to dilute tap water in a clean <br />truck -mounted 200 gallon plastic tank on-site. A ratio of approximately 5-7 parts clean water to one <br />part 50% hydrogen peroxide solution will be used, resulting in an 8% - 10% hydrogen peroxide <br />solution (25 — 33 gallons concentrate per 200 total gallons). Secondary containment beneath drums <br />will be used during mixing. Lines and valves will be wrapped with plastic to block spray from spills. <br />Technicians will watch for leaks in piping and spills, and neutralize with sodium metabisulfite as <br />needed. <br />Wellhead Preparation <br />Wells EX -1 and EX -2 will be fitted with a 4 -inch glued coupling and screwed plug, modified with a 30 <br />psi adjustable safety pressure relief valve, an injection port, manual pressure release valve, <br />temperature and pressure gauges (Figure 3). The inlet peroxide line will have a totalizer or some <br />other method to measure volume injected over time. All transfer piping and the top of EX -1 and EX - <br />2 well casing (except exhaust ports) will be wrapped in plastic to contain potential spills and leaks. <br />Exhaust ports should be vented to contain liquids and kept away from field personnel. Additional <br />quantities of dilute sodium metabisulfite solution will be kept onsite and the area surrounding the well <br />will be bermed to contain and neutralize potential spills. <br />The area will be marked with barricades, caution tape and signs warning of chemical hazards and no <br />smoking. A berm made of a non-absorbent sock will be installed around the treatment area and a <br />1:\Chevron\95775\REPORTS\Peroxide Injection WP RevB.doc SECOR International Incorporated <br />