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S E C 0 R <br />The difference between the estimated hydrocarbon mass and amount removed is most likely <br />attributable to isolated areas within the assessment area that contain higher contaminant <br />concentrations than previously identified. Also, the radius of influence captured by the SVE well <br />network was larger than originally estimated. These two factors were evaluated for updated <br />calculations; however, the updated calculations still showed greater than 200% mass removal <br />and are not included in this report. Thus, hydrocarbons were likely extracted from soil beyond <br />the boundaries of the original mass estimate calculations included in SECOR's June 5, 2001 <br />Problem Assessment Report/Final Remediation Plan Addendum. <br />4.3 Petroleum Hydrocarbons Dissolved in Groundwater <br />In A -Zone monitoring wells, MtBE was detected during the October 21, 2005 sampling event in <br />three of 13 wells sampled, including MW -13 at 0.6 gg/l, EX -1 at 160 µg/I, and EX -3 at 8 µg/1. <br />MtBE has been reported at concentrations of 1 µgAl or less for samples collected from MW -13 <br />during six quarterly monitoring events since sampling began in July 2000. Concentrations of <br />MtBE at wells EX -1 and EX -3 have dropped significantly since sampling began in March 2000 <br />and January 2001, respectively. Analytical results from groundwater samples collected October - <br />21, 2005 indicate TPHg and benzene concentrations are below laboratory reporting Iimit (Table <br />3). The lateral extent of MtBE in the A -Zone is defined by wells MW -1, MW -2, MW -3, MW -4, <br />MW -5A, MW -6, and MW -20A. Figure 8 illustrates the lateral extent of the plume in the A -Zone. <br />Figures 9 and 10 illustrate the declining trend of TPHg, benzene, and MtBE in wells EX -1 and <br />EX -2. Figure 11 illustrates the declining trend of TPHg and MtBE in well EX -3. <br />` In B -Zone monitoring wells, the maximum concentration of MtBE reported during the October <br />a <br />21, 2005 sampling event was found to be 2 pg/l, in well MW -513. Currently, TPHg and benzene <br />concentrations are below laboratory reporting limit in the B -Zone. The lateral extent of MtBE in <br />the B -Zone is defined by wells MW -713, MW -9B, MW -11 B, and MW -1213. <br />In C -Zone monitoring wells MW -10C and MW -19C, there are no constituents reported at or <br />above the laboratory reporting limit. <br />The S -Zone monitoring well (MW -8S) has not had any petroleum hydrocarbon constituents <br />detected above the laboratory reporting limits in the quarterly groundwater samples collected <br />from the monitoring well since May 2001, <br />95775 NFAR REPORT Final.doc 9 <br />SECOR lntemational Incorporated <br />ESTIMATED <br />MEVEDQ <br />SSREMAINING7777 <br />tsC"1S CITI]ENT <br />HYDROCARBQN <br />€ <br />THROUGH 3R" IN SOIL (lbs) 3 <br />PERCENTAGE <br />NIAs lbs <br />: <br />' 4 <br />QUARTER 2003 " f"a REMOV <br />QUARTER 20,3 ED <br />Gasoline <br />1,4501 <br />... ribs) <br />Hydrocarbons <br />4,132 <br />-2,682 <br />284 <br />Benzene <br />370 <br />85.9 <br />284.1 <br />23 <br />MtBE <br />67 <br />443.8 <br />-376.8 <br />662 <br />The difference between the estimated hydrocarbon mass and amount removed is most likely <br />attributable to isolated areas within the assessment area that contain higher contaminant <br />concentrations than previously identified. Also, the radius of influence captured by the SVE well <br />network was larger than originally estimated. These two factors were evaluated for updated <br />calculations; however, the updated calculations still showed greater than 200% mass removal <br />and are not included in this report. Thus, hydrocarbons were likely extracted from soil beyond <br />the boundaries of the original mass estimate calculations included in SECOR's June 5, 2001 <br />Problem Assessment Report/Final Remediation Plan Addendum. <br />4.3 Petroleum Hydrocarbons Dissolved in Groundwater <br />In A -Zone monitoring wells, MtBE was detected during the October 21, 2005 sampling event in <br />three of 13 wells sampled, including MW -13 at 0.6 gg/l, EX -1 at 160 µg/I, and EX -3 at 8 µg/1. <br />MtBE has been reported at concentrations of 1 µgAl or less for samples collected from MW -13 <br />during six quarterly monitoring events since sampling began in July 2000. Concentrations of <br />MtBE at wells EX -1 and EX -3 have dropped significantly since sampling began in March 2000 <br />and January 2001, respectively. Analytical results from groundwater samples collected October - <br />21, 2005 indicate TPHg and benzene concentrations are below laboratory reporting Iimit (Table <br />3). The lateral extent of MtBE in the A -Zone is defined by wells MW -1, MW -2, MW -3, MW -4, <br />MW -5A, MW -6, and MW -20A. Figure 8 illustrates the lateral extent of the plume in the A -Zone. <br />Figures 9 and 10 illustrate the declining trend of TPHg, benzene, and MtBE in wells EX -1 and <br />EX -2. Figure 11 illustrates the declining trend of TPHg and MtBE in well EX -3. <br />` In B -Zone monitoring wells, the maximum concentration of MtBE reported during the October <br />a <br />21, 2005 sampling event was found to be 2 pg/l, in well MW -513. Currently, TPHg and benzene <br />concentrations are below laboratory reporting limit in the B -Zone. The lateral extent of MtBE in <br />the B -Zone is defined by wells MW -713, MW -9B, MW -11 B, and MW -1213. <br />In C -Zone monitoring wells MW -10C and MW -19C, there are no constituents reported at or <br />above the laboratory reporting limit. <br />The S -Zone monitoring well (MW -8S) has not had any petroleum hydrocarbon constituents <br />detected above the laboratory reporting limits in the quarterly groundwater samples collected <br />from the monitoring well since May 2001, <br />95775 NFAR REPORT Final.doc 9 <br />SECOR lntemational Incorporated <br />