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V,_ <br />N <br />Laminate Construction <br />Composite products designed for corrosion resistance <br />typically utilize a structural laminate and a corrosion <br />barrier. This type of construction is necessary since the <br />overall properties of a composite are derived from the <br />widely differing properties of the constituent materials. <br />Glass fibers contribute strength but have little or no <br />corrosion resistance in many environments. Resins <br />provide corrosion resistance and channel stress into the <br />glass fibers and have little strength when unreinforced. <br />Consequently, a resin -rich corrosion barrier is used to <br />protect a glass -rich structural laminate. <br />In accordance with general industry practice, corrosion <br />barriers are typically 100-125 mils thick. They typically <br />consist of a surfacing veil saturated to a 90% resin <br />content, followed by the equivalent of a minimum <br />of two plies of 1.5 -oz to 2 -oz/ ft chopped strand mat <br />impregnated with about 70% resin. The structural <br />portion of the laminate can be built with chopped strand <br />mat, chopped roving, chopped strand mat alternating <br />with woven roving, or by filament -winding. An additional <br />ply of mat is sometimes used as a bonding layer <br />between a filament -wound structural over -wrap and <br />the corrosion barrier. Filament -wound structures have <br />a glass content of approximately 70% and provide high <br />strength combined with light weight. <br />Because resin provides corrosion resistance, a resin - <br />rich topcoat is often used as an exterior finish coat, <br />particularly where occasional contact or spillage with <br />aggressive chemicals might occur. UV stabilizers or <br />pigments may be incorporated into top coats (to minim- <br />ize weathering effects) or used in tanks designed to <br />contain light sensitive products. A top coat is especial- <br />ly useful forfilament-wound structures due to their high <br />glass content. <br />Surfacing Veil <br />A well -constructed corrosion barrier utilizing surface <br />veil is required for any polymer composite intended for <br />corrosion service. Veils based on C -glass, synthetic <br />polyester fiber and carbon are available. C -glass <br />veils are widely used because they readily conform to <br />complex shapes, are easy to wet out with resin and <br />provide excellent overall corrosion resistance. Synthetic <br />veils are harder to set in place and wet out, but can <br />provide a thicker, more resin -rich corrosion barrier. <br />The bulking effect of synthetic veil allows the outer <br />corrosion barrier to have a very high resin content, <br />which has both benefits and drawbacks. Higher resin <br />concentration can extend resistance to chemical and <br />abrasive attack, but also yields a corrosion barrier that <br />is more prone to cracking in stressed areas. This can <br />be an issue in corrosion barriers where multiple plies <br />of veil are used, and in areas where veil layers overlap. <br />Should the resin -rich veil portion of a corrosion barrier <br />crack, the barrier is breached and all of the benefits of <br />using multiple veils are lost. Furthermore, multiple plies <br />of synthetic veil can be more difficult to apply and often <br />lead to an increase in the number of air voids trapped <br />in the corrosion barrier. Many composite specifications, <br />including ASME RTP -1, impose a maximum allowable <br />amount of air void entrapment in the corrosion barrier. <br />Attempts to repair air voids are time-consuming and <br />can reduce the corrosion resistance of the composite. <br />Fabricators utilizing two plies of synthetic veil should <br />carefully follow the veil manufacturer's instructions and <br />also take special caution to ensure that no excessively <br />resin -rich areas are formed. Where a two-ply corrosion <br />barrier is desired, C -glass veil can be used for one or <br />both plies. This provides a degree of reinforcement to <br />the corrosion barrier, reduces resin drainage, and <br />creates a corrosion barrier that is less prone to <br />interlaminar shear cracking. <br />