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Selected Application Recommendations <br />Biomass and Biochemical Conversion <br />Applications have been increasing for processes <br />which transform biomass or renewable resources into <br />usable products. Most of the impetus has been energy <br />related, but the technology has diverse relevance, such <br />as various delignification processes associated with <br />elemental chlorine -free pulp production. Raw materials <br />include things like grain, wood, agricultural or animal <br />wastes, and high cellulose content plants. <br />Sometimes the processes involve pyrolysis or <br />gasification steps to break down the complex molecules <br />of the biomass into simpler building blocks such as <br />carbon monoxide or hydrogen, which in turn can be <br />used as fuels or catalytically synthesized into other <br />products, such as methanol. However, the most common <br />biochemical conversion process is fermentation, in <br />which simple sugars, under the mediation of yeasts or <br />bacteria, are converted to ethanol. With lingo -cellulose <br />or hemicellulose, the fermentation must be preceded by <br />thermochemical treatments which digest or otherwise <br />render the complex polymers in the biomass more <br />accessible to enzymatic breakdown. These enzymes <br />(often under acidic conditions) then enable hydrolysis of <br />starches or polysaccharides into simple sugars suitable <br />for fermentation into ethanol. Many of the conversion <br />steps have other embodiments, such as the anaerobic <br />digestion to produce methane for gaseous fuel. <br />A great deal of technology and genetic engineering is <br />evolving to enable or to improve the efficiency of these <br />processes. It is expected that many of the process <br />conditions can often be quite corrosive to metals, and <br />FRP composites can offer distinct benefits. <br />Bleaching Solutions <br />Bleach solutions represent a variety of materials <br />which display high oxidation potential, These include <br />compounds or active radicals like chlorine, chlorine <br />dioxide, ozone, hypochlorite or peroxide. Under most <br />storage conditions these materials are quite stable, but <br />when activated, such as by changes in temperature, <br />concentration, or pH, the bleaches are aggressive and <br />begin to oxidize many metals and organic materials, <br />including resins used in composites. Thus, resins <br />need to display resistance to oxidation as well as to <br />the temperature and pH conditions employed in the <br />process. Most interest centers on bleaching operations <br />employed in the pulp and paper industry, but similar <br />considerations apply to industrial, disinfection, and <br />water treatment applications. <br />Bleach solutions are highly electrophilic and attack <br />organic materials by reacting with sources of electrons, <br />of which a readily available source is the residual <br />unsaturation associated with an incomplete cure. <br />Consequently, the resistance of composites to bleach <br />environments demands a complete cure, preferably <br />followed by post -curing. Since air -inhibited surfaces are <br />especially susceptible to attack, a good paraffinated <br />topcoat should be applied to non -contact surfaces, <br />including the exterior, which may come into incidental <br />contact with the bleach. <br />BPO/ DMA curing systems are sometimes advocated <br />for composites intended for bleach applications due to <br />concerns over reaction with cobalt promoter involved <br />in conventional MEKP/ DMA curing systems. While <br />BPO/ DMA curing can offer appearance advantages, <br />the conventional MEKP/ cobalt systems yield very <br />dependable and predictable full extents of curing and <br />thus have a good history of success. <br />