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Common Types of Metal Corrosion <br />Hydrogen Embrittlement <br />Atomic hydrogen can diffuse or become adsorbed into <br />steel. It then reacts with carbon to form methane or <br />microscopic gas formations which weaken and detract <br />from ductility. Usually this happens at high temperature <br />under conditions where FRP is ordinarily notconsidered. <br />The same type of mechanism of attack is associated <br />at lower temperatures with various forms of galvanic <br />or stress induced corrosion. Quite often hydrogen <br />embrittlement can be a problem for steel which has <br />been electroplated or pickled, especially when done <br />improperly or inefficiently. Some of these matters are <br />receiving more attention due to future considerations of <br />hydrogen in fuel cell and other energy applications. <br />Sulfate Reducing Bacteria and Microbially Induced <br />Corrosion (MIC) <br />Colonies of microorganisms, especially aerobic and <br />anaerobic bacteria contribute greatly to corrosion of <br />steel through a wide variety of galvanic and depositional <br />mechanisms. Usually the corrosion is manifested in the <br />form of pitting or sulfide induced stress cracking. Perhaps <br />the most significant type of such corrosion involves <br />sulfate -reducing bacteria (SRB), which metabolize <br />sulfates to produce sulfuric acid or hydrogen sulfide. <br />Such bacteria are prolific in water (including seawater), <br />mud, soil, sludge, and other organic matter. <br />L: <br />These bacteria are a major reason why underground <br />steel storage tanks are corroded, and this has <br />lead to widespread use of FRP as an alternative or <br />as an external protective barrier to steel. Various <br />manifestations of MIC are seen far -and wide, including <br />industrial environments which inadvertently serve as <br />warm or nutrient -rich cultures for biological growth. <br />FRP is unaffected by many of the mechanisms <br />associated with MIC. <br />Apart from sulfate reducing bacteria, other forms of <br />microbial corrosion which affect metals include acid <br />producing bacteria, slime forming organisms, denitrifying <br />bacteria which generate ammonia, and other corrosion <br />associated with various species of algae and fungi. <br />It is expected that biologically induced corrosion will <br />receive increased attention as more applications and <br />technologies evolve in the field of energy production <br />associated with biomass and renewable resources. <br />Processing will include such things as aerobic and <br />anaerobic digestion, fermentation, enzymatic hydrolysis <br />and conversion of cellulose, lignin, or polysaccharides <br />to sugars, which in turn may be converted to ethanol. <br />Carbon and stainless steels are not the only metals <br />affected by MIC. Also routinely corroded are copper and <br />various alloys as well as concrete. The most common <br />example of which involves sewage and waste treatment <br />applications in the presence of the thiobacillus bacteria, <br />which oxidizes 1-12S to sulfuric acid. FRP has a long <br />history of successful use in these environments. <br />