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Ms. Kathy Amaru <br /> Estimates of Contaminants in Soil4k Groundwater . <br /> PG&E McMullin Natural Gas Dehydration Station <br /> April 25, 2008 <br /> • To determine the average concentration of hydrocarbons in the volume of soil defined by the <br /> polygon, the impacted soil sample concentration and '/ of the corresponding ND detection limit <br /> were averaged; <br /> • In-place soil density was estimated at 130 ib/ft3 (59 kglft3). <br /> After determining the above data, the following equations were used to estimate the mass of each <br /> contaminant remaining in soil. Inputs and results to these equations are depicted in Table A. <br /> C, f� <br /> Si = 2 Xy, Xp <br /> s = Is; <br /> Where: <br /> C; = The detected contaminant concentration in soil in the ith polygon; <br /> R = The reporting limit of the detected contaminant; <br /> V;= The volume of impacted soil in the ith polygon; <br /> Si= The mass of contaminant remaining in soil in the ith polygon; <br /> p = Soil density; and <br /> S = The total mass of contaminant remaining in soil. <br /> Estimate of Contaminants Remaining in Groundwater <br /> To estimate the mass of contaminants in groundwater the following data were required: the <br /> hydrocarbon concentrations in groundwater, the volume of water to be considered, and soil porosity. <br /> Once these data were compiled, a calculation of remaining hydrocarbon mass was possible. To <br /> determine these data, the following assumptions were made: <br /> • All contaminant concentrations are assumed to be '/ of the detection limits for the estimation <br /> because no contaminants were detected in the most recent groundwater monitoring event of May <br /> 2004; <br /> • Mass of remaining contaminants is estimated within Site boundaries of 85ft x 100ft, and vertically <br /> from the top of the groundwater table (as measured in the groundwater monitoring event of May <br /> 2004) to 16ft (depth of the 2002 excavation at the Site); and <br /> • Soil porosity is assumed to be 50%. <br /> The above data were used as inputs to calculate the mass of hydrocarbons in groundwater. The inputs <br /> and results of calculations are depicted in Table B. <br /> Page 2 of 3 <br />