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Mr. Fernando Amador -2- 2 July 1996 <br />have been generally decreasing over time; (5) PNAs were also detected in Zone B beneath Area H of <br />the site; and (6) other historic sources of petroleum hydrocarbons (former service stations) were <br />located near Area II. <br />It is not clear what is meant by "The extent of PNAs in Zone B has been confirmed beneath Area I." <br />The simple fact remains that the extent of PNA contamination in Zone B has not been defined. It is <br />also not clear if the report is suggesting that the former service stations located near Area II are the <br />source of PNAs in Zone B beneath Area II. PG&E should compare the PNAs present in fuel <br />petroleum hydrocarbons with those present in the ground water beneath Area II to determine the <br />latter's origin. If the PNAs present in ground water are not PNAs which are associated with fuel <br />petroleum hydrocarbons, then PG&E is the likely source of ground water contamination in Zone B <br />in Area II. <br />2. Page ES -2, Executive Summary <br />The report states that PNAs were detected in hydropunch samples from Zone A in MW -14 and from <br />Zones A and B in MW -15 during the drilling of these Zone C wells. The report also states that since <br />these wells are upgradient of the site, there could be upgradient sources of the PNAs in ground <br />water. However, the presence of PNAs in ground water in Zone A at MW -14 and PNAs in Zones A <br />and B at MW -15 has not been confirmed because of the absence of monitoring wells (MWs) at these <br />locations. Furthermore, all the MWs which show PNA contamination around PG&E could have <br />been contaminated by PG&E due to ground water elevation fluctuations and flow reversals. Some <br />evidence of flow reversal is shown in Table 3-4. In addition, the MWs at the Fire Department <br />(northwest of PG&E) show a Zone A ground flow direction to the northeast which differs from <br />PG&E Zone A ground water flow direction which is predominantly to the east. This could be an <br />artifact of flow reversal or some hydrogeologic condition which results in different ground water <br />flow directions in Zone A. Also, onsite and offsite ground water elevations have only been measured <br />since 1992. The plant started operations in the 1800s. It is likely that ground water flow reversals <br />and fluctuations occurred over the years and could have resulted in the formation of pockets of <br />contamination which are now contributing sources to the overall contamination coming from <br />locations of former MGP structures. For example, MW -14 is only approximately 70 feet west of <br />NT IO '-1R and 1`. IN- D, both of which have PNA contamination. The proximity of MW -14 to onsite <br />MWs showing contamination, the very flat gradient, and the potential for flow reversal suggest that <br />MW -14 has been impacted by onsite contamination. <br />3. Page ES -2, Executive Summary <br />The report states that there is no current risk from constituents of potential concern (COPCs) in soil <br />or ground water since no complete exposure pathway exists as determined by a risk assessment <br />(RA). This is not an accurate statement because the RA did not consider ground water as a <br />receptor. Since ground water is a receptor and has already been impacted, a complete pathway does <br />exist. <br />