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WASTE DISCHARGE REQUIREMEN410RDER NC R5-2012-0106 <br /> -4- <br /> GLENN SPRINGS HOLDING COMPANY, <br /> FORMER OCCIDENTAL CHEMICAL COMPANY, GROUNDWATER REMEDIATION PROJECT, LATHROP FACILITY <br /> SAN JOAQUIN COUNTY <br /> removed approximately 12,300 pounds (lbs) of sulfolane, 4,000 lbs of DBCP, and 220 <br /> lbs of EDB. <br /> 18. EDB and DBCP have not been detected in the injection zone monitoring wells below the <br /> Corcoran Clay since at least 1998. The best currently approved analytical methods for <br /> DBCP have detection levels of 0.001 erg/L and practical quantitation levels of 0.01 pg/L. <br /> The practical. quantitation level is above the effluent limitation for DBCP found in this <br /> Order. Compliance with the effluent limitation is demonstrated by measuring no <br /> detectable concentrations of DBCP when using the method(s) listed on MRP R5-2012- <br /> 0106 and achieving the specified method detection limit. If new methods are approved <br /> that improve on the detection level and practical quantitation level, the MRP will be <br /> revised. <br /> 19. Based on the most recent data collected in August and September 2011, sulfolane is <br /> present in injection zone.monitoring wells PW09-338 and PW12-315 at 65 pg/L and <br /> 170 pg/L, respectively. There was no treatment goal for sulfolane until 1992, so <br /> concentrations of sulfolane in the injection zone reflect the injection of untreated <br /> sulfolane from 1982 to 1992 and concentrations in the injectant that were below the <br /> previous discharge limit of 57 pg/L established after 1992. <br /> 20. Total dissolved solids (TDS) in the.injection zone monitoring wells averages 2,479 <br /> milligrams per liter (mg/L) with a maximum concentration of 4,860 mg/L. The highest <br /> TDS concentrations were measured west of the Site, in PW20-500, where groundwater <br /> quality-is most affected by saline water from the San Francisco Bay Delta. Chloride <br /> accounts for the majority of TDS in PW20-500. TDS concentrations in treatment system <br /> effluent average 2,369 mg/L with a maximum concentration of 3,150 mg/L. Sulfate <br /> accounts for the majority of TDS in the treatment system effluent. TDS concentrations in <br /> the treatment system effluent are expected to stay within the same range after the <br /> proposed additional extraction wells begin operation. <br /> SURFACE AND GROUND WATER CONDITIONS <br /> 21. The first water-bearing zone (water table zone) beneath the Site occurs at a depth of 10 <br /> to 19 bgs. A shallow zone occurs at depths of approximately 50 to 100 feet bgs. An <br /> intermediate water-bearing zone occurs at depths of 100 to 150 feet bgs, and a deep <br /> aquifer is present at depths of 150 to 200 feet bgs. Water level measurements across <br /> the site indicate that there is hydraulic connection between the water-bearing zones <br /> above the Corcoran Clay. Saline groundwater occurs in locations west of the Site. <br /> GROUNDWATER MONITORING <br /> 22. As part of the groundwater remedial action, the Discharger performs groundwater <br /> monitoring pursuant to Monitoring and Reporting Program (MRP) Order No. R5-2004- <br /> 0800. <br />