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UAN 32% Section 4. First aid measures Eye contact Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Skin contact Wash skin thoroughly with soap and water or use recognized skin cleanser. Get medical attention if irritation occurs. Remove contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Inhalation Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth- to-mouth resuscitation. Get medical attention if symptoms occur. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Ingestion Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs,the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 5. Fire fighting measures Flammability of the product : May be combustible at high temperature. Products of combustion : These products are carbon oxides(CO, CO2), nitrogen oxides(NO, NO2 etc.), ammonia (NH3). Fire-fighting media and : Use water only in flooding quantities. Do NOT use chemical extinguisher or foam or instructions attempt to smother the fire with steam or sand.Do not release runoff from fire to sewers or waterways. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus(SCBA)with a full face-piece operated in positive pressure mode. Special remarks on fire : The product itself is not combustible but it can support combustion, even in absence of hazards air. Section 6. Accidental release measures Personal precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment. Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil,waterways, drains and sewers. Methods for cleaning up : If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent(soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Section 7. Handling and storage Handling : Avoid contact with eyes, skin and clothing. Ensure that eyewash stations and safety showers are close to the workstation location. Storage : Do not store above 60° C.The tank/container should be placed within a bunker able to take the whole tank/container volume. Store ix`l.�10m area. t JUN 0 6 2014 ENVIRONMENTAL HEALTH DEPARTMENT Page:215