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UNLEADED GASOL• UNADDITIZED (s) <br /> ' HANDLING PRECAUTIONS <br /> This liquid is volatile and gives off invisible vapors. Either the liquid or <br /> vapor may settle in low areas or travel some distance along the ground or <br /> surface to ignition sources where they may ignite Or explode. <br /> ' Keep product away from ignition Sources, such as heat , sparks, pilot lights, <br /> static electricity, and open flames. <br /> FLAMMABLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT BY VOLUME IN AIR) <br /> Estimated values: Lower Flammable Limit 1 .4% Upper Flammable Limit 7.6% <br /> EXTINGUISHING MEDIA AND FIRE FIGHTING PROCEDURES <br /> Foam, water Spray ( fog) , dry chemical , carbon dioxide and vaporizing liquid <br /> type extinguishing agents may all be suitable for extinguishing fires <br /> involving this type of product , depending on size or potential size of fire <br /> and circumstances related to the situation. Plan fire protection and response <br /> strategy through consultation with local fire protection authorities or <br /> appropriate specialists. <br /> The following procedures for this type of product are based on the <br /> recommendations in the National Fire Protection Association's "Fire Protection <br /> Guide on Hazardous Materials" , Tenth Edition ( 1991 ) : <br /> Use dry chemical , foam or Carbon dioxide to extinguish the fire. Water may be <br /> ineffective, but water should be used to keep fire-exposed containers cool . <br /> If a leak or spill has ignited, use water spray to disperse the vapors and to <br /> protect men attempting to stop a leak. Water spray may be used to flush <br /> spills away from exposures. Minimize breathing of gases, vapor , fumes or <br /> decomposition products. Use supplied-air breathing equipment for enclosed or <br /> confined spaces or as otherwise needed. <br /> NOTE: The inclusion of the phrase "water may be ineffective" is to indicate <br /> that although water Can be used to Cool and protect exposed material , water <br /> may not extinguish the fire Unless used under favorable conditions by <br /> experienced fire fighters trained in fighting all types of flammable liquid <br /> fires. <br /> DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS <br /> Fumes, smoke, carbon monoxide, Sulfur oxides, aldehydes and other <br /> decomposition products, in the case of incomplete combustion. <br /> "EMPTY" CONTAINER WARNING <br /> "Empty" containers retain residue ( liquid and/or vapor) and can be dangerous. <br /> DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH <br /> ' CONTAINERS TO HEAT, FLAME, SPARKS , STATIC ELECTRICITY, OR OTHER SOURCES OF <br /> IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to clean <br /> since residue is difficult to remove. "Empty" drums should be completely <br /> drained, properly bunged and promptly returned t0 a drum reconditioner . All <br /> other containers should be disposed of in an environmentally safe manner and <br /> in accordance with governmental regulations. For work on tanks refer to <br /> Occupational Safety and Health Administration regulations, ANSI Z49. 1 , and <br /> other governmental and industrial references pertaining to cleaning, <br /> repairing, welding, or Other contemplated operations. <br /> E. HEALTH AND HAZARD INFORMATION <br /> ' VARIABILITY AMONG INDIVIDUALS <br /> Health studies have shown that many petroleum hydrocarbons and synthetic <br /> lubricants pose potential human health risks which may vary from person to <br /> person. As a precaution, exposure t0 liquids, vapors, mists Or fumes should <br /> be minimized. <br /> EFFECTS OF OVEREXPOSURE (Signs and symptoms of exposure) <br /> High vapor Concentrations (greater than approximately 1000 ppm) are irritating <br /> ' to the eyes and the respiratory tract , and may cause headaches, dizziness, <br /> anesthesia, drowsiness, unconsciousness, and Other Central nervous system <br /> effects, including death. <br /> Prolonged Or repeatetl 11gUttl Contact with the Skin will dry and def at the <br /> skin, leading to possible irritation and dermatitis. <br /> ses-OaniMwnOoa; DATE ISSUED: 09/15/93 <br /> PAGE : 3 SUPERSEDES DATE : 09/11 /92 <br />