Laserfiche WebLink
There is another problem associated with using a vadose zone monitoring system at this <br /> particular site. Due to the fine-grained, low permeability nature of the native soils located at <br /> the subject site, either vapor monitoring or soil pore liquid monitoring is a highly unreliable <br /> means of vadose zone monitoring. Lysimetry is not effective in fine-grained sediments (7). <br /> Further, AEMC contends that the amount of soil pore liquid required for laboratory analyses <br /> (approximately 32 ounces) cannot be collected on a consistent basis from the native soils to <br /> effectively conduct a monitoring program based on lysimetry. In addition, clogging of the <br /> porous membrane at the lysimeter tip is very possible due to the fine-grained nature of the <br /> native soils, thereby rendering the lysimeter useless for its intended purpose (7). There is also <br /> the high probability that false positives or negatives in the lab analyses can occur through the <br /> use of lysimetry (7). <br /> Generally, soil-gas sampling is most applicable to sites at which the vadose zone is <br /> characterized by dry, coarse-grained soils containing minimal organic carbon (5). Fine- <br /> grained soils tend to have a relatively low air-filled porosity and trap moisture and organic <br /> material that can act as a sink for VOC's (5). In addition, compounds that possess low vapor <br /> pressures do not diffuse adequately in soil gas (4). For these reasons, AEMC considers soil- <br /> gas, or vapor, monitoring inappropriate for monitoring the #6 fuel oil tank. <br /> It is for this reason that AEMC proposes that, in addition to a regular groundwater monitoring <br /> program, a daily inventory reconciliation program could be carried out in accordance with <br /> California Administrative Code Title 23, Chapter 3, Subchapter 16, Article 4, Section 2644, <br /> "Inventory Reconciliation," where applicable, to fulfill the requirement for a vadose zone <br /> monitoring system and eliminate the need for a variance to Monitoring Alternative #2. Since <br /> Inventory Reconciliation is a monitoring alternative normally used for motor-fuel storage <br /> tanks, some modification of section 2644 may be required. <br /> Page 3 <br />