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L��_Torrent 1Atl011AIONY. 11C Laboratory Qualifiers and Definitions DEFINITIONS: Accuracy/Bias (% Recovery) - The closeness of agreement between an observed value and an accepted reference value. Blank (Method/Preparation Blank) -MB/PB - An analyte -free matrix to which all reagents are added in the same volumes/proportions as used in sample processing. The method blank is used to document contamination resulting from the analytical process. Duplicate - a field sample and/or laboratory QC sample prepared in duplicate following all of the same processes and procedures used on the original sample (sample duplicate, LCSD, MSD) Laboratory Control Sample (LCS ad LCSD) - A known matrix spiked with compounds representative of the target analyte(s). This is used to document laboratory performance. Matrix - the component or substrate that contains the analyte of interest (e.g., - groundwater, sediment, soil, waste water, etc) Matrix Spike (MS/MSD) - Client sample spiked with identical concentrations of target analyte (s). The spiking occurs prior to the sample preparation and analysis. They are used to document the precision and bias of a method in a given sample matrix. Method Detection Limit (MDL) - the minimum concentration of a substance that can be measured and reported with a 99% confidence that the analyte concentration is greater than zero Practical Quantitation Limit (PQL) - a laboratory determined value at 2 to 5 times above the MDL that can be reproduced in a manner that results in a 99% confidence level that the result is both accurate and precise. PQLs reflect all preparation factors and/or dilution factors that have been applied to the sample during the preparation and/or analytical processes. Precision (%RPD) - The agreement among a set of replicate/duplicate measurements without regard to known value of the replicates Surrogate (S) or (Surr) - An organic compound which is similar to the target analyte(s) in chemical composition and behavior in the analytical process, but which is not normally found in environmental samples. Surrogates are used in most organic analysis to demonstrate matrix compatibility with the chosen method of analysis Tentatively Identified Compound (TIC) - A compound not contained within the analytical calibration standards but present in the GCMS library of defined compounds. When the library is searched for an unknown compound, it can frequently give a tentative identification to the compound based on retention time and primary and secondary ion match. TICS are reported as estimates and are candidates for further investigation. Units: the unit of measure used to express the reported result - mglL and mg/Kg (equivalent to PPM - parts per million in liquid and solid), ug/L and ug/Kg (equivalent to PPB - parts per billion in liquid and solid), ug/m3, mg.m3, ppbv and ppmv (all units of measure for reporting concentrations in air), % equivalent to 10000 ppm or 1,000,000 ppb), ug/Wipe ( concentration found on the surface of a single Wipe usually taken over a 100cm2 surface) LABORATORY QUALIFIERS: B - Indicates when the anlayte is found in the associated method or preparation blank D - Surrogate is not recoverable due to the necessary dilution of the sample E - Indicates the reportable value is outside of the calibration range of the instrument but within the linear range of the instrument (unless otherwise noted) Values reported with an E qualifier should be considered as estimated. H- Indicates that the recommended holding time for the analyte or compound has been exceeded J- Indicates a value between the method MDL and PQL and that the reported concentration should be considered as estimated rather the quantitative NA - Not Analyzed N/A - Not Applicable NR - Not recoverable - a matrix spike concentration is not recoverable due to a concentration within the original sample that is greater than four times the spike concentration added R- The % RPD between a duplicate set of samples is outside of the absolute values established by laboratory control charts S- Spike recovery is outside of established method and/or laboratory control limits. Further explanation of the use of this qualifier should be included within a case narrative X -Used to indicate that a value based on pattern identification is within the pattern range but not typical of the pattern found in standards. Further explanation may or may not be provided within the sample footnote and/or the case narrative. 483 Sinclair Frontages Rd_, Milpitas. CA 95035 r,-1 408.263.5258 1 f.ix: 409.263.8293 1 www.torrretitiab.com Total Page Count: 15 Page 12 of 15