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Mr. Juston Smithers <br />-3- <br />11 <br />February 11, 2015 <br />As indicated in the laboratory report, the only organic constituent that was detected in the <br />analysis following the TCLP extraction was dimethyl phthalate. There is no TCLP threshold <br />for dimethyl phthalate. Therefore, the test results indicate that the ash does not exhibit a <br />RCRA characteristic of toxicity. In absence of any detected TCLP organic constituents and <br />based on the low likelihood that significant concentrations of organic constituents would be <br />present in the ash, ENVIRON concludes that a single sample is sufficient for assessing the <br />potential for RCRA toxicity due to organics. <br />Based on the above-described test results, the ash would be classified as a non-RCRA hazardous <br />waste in California. <br />Waste Characterization of DPF Units <br />DPFs are generally in one of the following configurations: <br />• DPFs comprised of an outer metal casing coated with a substrate (usually ceramic) that <br />contains precious metals (e.g., platinum, palladium); <br />• Uncoated DPFs that are made of ceramic and do not contain precious metals; <br />• Uncoated DPFs that are made of stainless steel and do not contain precious metals; or <br />All DPFs may contain small amounts of the ash that was characterized in the preceding section of <br />this letter. The DPFs are evaluated for potential waste characteristics attributable to zinc in the ash <br />and platinum in the substrate, as described below. <br />Red Fox will also collect non-DPF catalysts comprised of flow-through substrates that have <br />honeycombs coated with precious metals. ENVIRON understands that flow-through catalysts are <br />much less likely to contain a significant amount of ash as they do not trap particles in the same <br />manner as DPFs, and that the weight proportion of ash in non-DPF catalysts is much smaller than in <br />the DPF catalysts. <br />Zinc in DPFs <br />The DPFs may potentially exhibit a characteristic of hazardous waste if the quantity of ash present in <br />the DPF is large enough to impart a characteristic to the entire DPF. Based on the information you <br />provided, a typical weight for a DPF is 21 kilograms and the quantity of ash within the DPF is typically <br />500 grams to 1,000 grams (0.5 to 1 kilogram); we understand that 44 Energy Tech has determined <br />that it is extremely unlikely that the proportion of ash in a DPF would exceed the upper bound <br />reflected by these weights. The concentration of zinc in the four samples tested ranged from 29,000 <br />mg/kg to 70,000 mg/kg. Based on these results, the range of zinc concentrations in the DPF would <br />be as follows: <br />Minimum zinc in DPF = 29,000 mg/kg x 0.5 kg = (21 kg + 0.5 kg) <br />674 mg/kg <br />Maximum zinc in DPF = 70,000 mg/kg x 1 kg = (21 kg + 1 kg) <br />= 3,182 mg/kg <br />0 <br />