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ATTACHMENTC <br /> FIELD AND LABORATORY PROCEDURES <br /> Chevron 9-4275, 2905 Benjamin Holt Drive, Stockton, CA <br /> • CPT INVESTIGATION <br /> Health and Safety <br /> As required by the Occupational Health and Safety Administration (OSHA) Standard <br /> "Hazardous Waste Operations and Emergency Response" guidelines (29 CFR 1910 120), <br /> and by California Occupational Health and Safety Administration (Cal-OSHA) <br /> "Hazardous Waste Operations and Emergency Response" guidelines (CCR Title 8, <br /> Section 5192), SECOR prepared a Site-Specific Health and Safety Plan for use during <br /> fieldwork The field staff and contractors reviewed the Site-Specific Health and Safety <br /> Plan before beginning field operations at the site <br /> Exploratory Drilling and Soil and Groundwater Sampling <br /> The CPT soil borings were advanced using a direct push cone penetrometer testing <br /> (CPT) ng to log soil stratigraphy Immediately adjacent to each CPT borehole, a second <br /> direct-push borehole was advanced to collect discrete groundwater samples <br /> Groundwater samples were collected using a hydropunch, or similar technology, by <br /> lowering a stainless steel or Teflon bailer into accumulated groundwater in the borehole, <br /> then retrieving and transferring the water into laboratory supplied containers The <br /> groundwater sample containers were placed on ice for transport to the laboratory <br /> accompanied by chain-of-custody documentation Down-hole boring and sampling <br /> equipment was steam-cleaned prior to and following the completion of each soil boring <br /> Down-hole sampling equipment was washed in a tri-sodium phosphate or AlconoxTM <br /> solution between samples <br /> Organic Vapor Procedures <br /> Soil samples collected continuously during drilling were analyzed in the field for <br /> ionizable organic compounds using a photo-ionization detector (PID) with a 10 2 eV <br /> lamp or a flame ionization detector(FID) The test procedure involved measuring <br /> approximately 30 grams from an undisturbed soil sample, placing this sub-sample in a <br /> sealed container (either a zip-lock bag or a mason far) The container was warmed for <br /> approximately 20 minutes (in the sun), then the head-space within was tested for total <br /> organic vapor, measured in parts per million as benzene (ppmv, volume/volume) The <br /> instrument was calibrated prior to drilling using a 100-ppm isobutylene standard (in air) <br /> and a sensitivity factor of 55, which relates the photo-ionization potential of benzene to <br /> that of isobutylene at 100 ppm The results of the field-testing was noted on the boring <br /> logs PID and FID readings are useful for indicating relative levels of contamination, but <br /> cannot be used to evaluate hydrocarbon levels with the confidence of laboratory <br /> analyses <br />