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No. 385 =YL $EN N7E ]1/80 �-✓
<br /> SECTION 6. HEALTH HAZARD INFORMATION, cont.-
<br /> flush
<br /> ont.flush cues,including under-the eyelids,gentlybut thoroughly With flooding amounts of running wafer for at least 1S minutes:Skin.Rinse
<br /> the affected area with plenty of water,then wash ii with soap and water.Inhalation.Remove the exposed person Go fresh air,restore and/or
<br /> support his or her breathing.as needed.Have qualified medical personnel administer oxygen as required.Ingestion:Unlikely.Should -
<br /> this type of exposure occur,the aspiration hazard must be considered.,Do not induce vomiting unless directed to do so by a physician.To
<br /> prevent aspiration by spontaneous vomiting,keep the victim's head low(between his or her knees).Get medical help(in plant,para-
<br /> medic,community)for all exposures.Seek prompt medical assistance for further treatment,observation;and support after first aid.Note
<br /> to Physician: Professional judgment is required as to whether or not to induce vomiting because of the possibility of aspiration.A gastric I
<br /> lavage.may-be administered,followed by saline catharsis,if this procedure is appropriate to the specific inciden" t.Monitor cardiac and i
<br /> pulmonary functions. � 0 �. .� ,;. .. .. t
<br /> SEGTION: '7. :;°SPILL, "LEAK, :AND DISPOSAL'`.PROCEDURES" '�
<br /> S}W/Leak: Notify safety personnel,evacuate unnecessary personnel',eliminate all sources of ignition immediately,and provide adequate',+
<br /> explosion-proof ventilation.Cleanup personnel need protection against skin or eve contact with this liquid as"well as-inhalation of its vapor, :
<br /> (see'sect.8).Contain large spills and collect waste or absorb it with an inert material such as sand,earth,or vermiculite.Use nonsparking
<br /> tools to place waste liquid or absorbent into closable containers for disposal.Keep waste out of sewers,watersheds,and waterways.Waste
<br /> Disposal: Contactyouur supplier or a licensed contractor for detailed recommendations.Follow Federal,state,and local regulations.
<br /> OSHA°Desigeafions
<br /> r
<br /> Listcd as as Air Contaminant(29 CFR 1910.1000 Subpart Z).
<br /> EPA Designations(40 CFR 302.4) - •
<br /> CERCLA Hazardous Substance,Reportable Quantify:'1000 lbs(454 kg),per the Clean Water Act(CWA), 311 (b)(4)and 307(a). j
<br /> j
<br /> SECTION " 8. SPECIAL PROTECTION ,INFORMATION'
<br /> Goggles: Always wear protective eyeglasses or chemical safety goggles. Where splashing is possible,wear a full face shield.Foliow j
<br /> OSHA eye-and face-protection regulations(29 CFR 1910.133).Respirator: Wear a NIOSH-approved respirator per Geni um.reference 88
<br /> for the maximum-use concentrations and/or the exposure limits cited in section 2.Follow OSHA respirator regulations(29 CFR 1910.134).
<br /> For emergency or nonroutine operations(spills or cleaning reactor vessels and storage tanks),wear an SCBA.Warning: Air-purifying
<br /> respirators will'noi protect workers in oxygen-deficient atmospheres.Other: Wear impervious gloves,boots,aprons,and gauntlets;etc„to= ;
<br /> prevent prolonged or repeated skin contact with this material.Ventilation: Install and operate general-and local maximum,.expiosion-proof
<br /> "ventilation systems powerful enough to maintain airborne levels.of this material below the OSHA PEL standard cited in section 2.Local
<br /> exhaust ventilation is preferred because it prevents,dispersion of the contaminant into the general work a>ea by.eliminafing it at its source.,;
<br /> Consult the latest edition of Geaium reference.103 for detailed recommendations.Safety Stations: Make emergency eyewash stations;
<br /> safetyiquick-drench showers,and washing facilities available in work areas.Contaminated Equipment; Contact lenses pose a special ` I
<br /> hazard;soft lenses may absorb irritants,and all lenses concentrate them.Do not wear contact lenses in airy work area'Remove contatrii-—
<br /> Dated clothing and launder it before wearing it again;clean this material from shoes and equipment.Comments:'Practice good personal
<br /> hygiene;always wash thoroughly after using this material and before eating,drinking,smoking,using the toilet,or applying.cosmetics-.
<br /> Keep it off your clothing and equipment,Avoid transferring it from your hands to your mouth while eating,drinking,or smoking.Do nor ,,
<br /> eat,drink,or smoke in any.work area.Do not inhale ethyl benzene vapor.
<br /> SECTION °9. `SPECIAL PRECAUTIONS AND ';COMMENTS :47
<br /> Storage/Segregation--Store ethvl benzene in closed containers in a cool,do',"well-ventiiated area away frdm,sources of'ignition and '-
<br /> strong oxidizers.Protect containers frrom physical damage.Special Handling/Storage: Outside,isolated,detached,orremote"storage is
<br /> recommended for large quantities of ethyl benzene.lsolatc bulk storage areas from acute fire hazards.Engineering Controls: Make sure
<br /> all engineering systems(production,transportabon)are of maximum explosion-proof design.To prevent static sparks,electrically ground
<br /> and bond all rontainers,pipelines,etc.,used in shipping,transferring,reacting,production,and sampling operations.Other- Use safety .
<br /> cans for transferring small amounts of ethyl benzene.'
<br /> Transpkirtatiaii Date(49 CFR
<br /> ; DOT Shipping?xame:'Ethy)Benzene .« +fi- - ..ry,. .� ""« . F „ . :• x
<br /> DOTHazard Class:,.Flammable liquid � !Per.. y � I
<br /> ID No.UN1175
<br /> DOT Label. Flammable•Liquid'
<br /> DOT.Packaging Exceptions: 49 CFR 173 118 Y
<br /> DOT Packaging Requirements: 49 CFR 173119
<br /> LIMO Shipping lame. Ethylbenzene �'�� «• r "j • r ,.i t
<br /> EMO Hazard Class: 3.2
<br /> Ih40 Label: Flammable Liquid I
<br /> IMDG Packaging Group:,11, �� 4'f
<br /> `References:'I,26,38,84-94, 100,116, 117, 120;_122.
<br /> 3udgmenu ac to the auita5ikm'of informauoa hails for purchasers purpose:are
<br /> i
<br /> neceaaanlppurcha%crsrmponsibilitv.Therefore,alihouoTumonablecare has, t PrepdbVI�JIf�*o2.,-�S
<br /> - beta Takeo is the preparauna of such iaforma:,oa,Gcnmm F`ubhs7ung Carp. *''
<br /> exteads anwarrantfes,makrs no mprescotations and sssumes no mponslbility..;;t Industrial Hygiene Review., D3.Wilsor, CIH -
<br /> as.to the acearacv or witabjlits'of such infa.7nxion for apphutron to .
<br /> purchaser's intended putvoaca or for consccum=of its use. Medical Review: W Si}verYrtan,MD
<br /> ". - Y .r a,yr Lr ate, + - , - e.aw l 'prwY• a_+dyrr'. .! - z, rt y
<br /> 'coPyr7Rbt O 1988 by Gcai»Put]islmR Caporetion
<br /> Any Mn=WCW use or rtproouetim wimmt tre;wht Wvr's permission a prohibimC •. *rr.c.• .b' x f _ ..{'.
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