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SITE CLOSURE REQUEST REPORT <br /> Former Exxon Service Station No.7-3330 <br /> • 3128 West Benjamin Holt Drive <br /> Stockton,California <br /> Delta Project No. D093-810 <br /> Page 14 <br /> in these processes include aerobic (oxygen enriched) and anaerobic (oxygen deficient) biodegradation, <br /> dispersion, volatilization, and adsorption. Of these processes, biodegradation is related to the natural <br /> reduction of the petroleum hydrocarbon constituent mass. <br /> There are differences between aerobic and anaerobic biodegradation. Aerobic biodegradation consumes <br /> oxygen which is used as the catalyst for the chemical breakdown of petroleum hydrocarbon constituents <br /> to carbon dioxide and water. Aerobic biodegradation may occur when dissolved oxygen(DO) is present <br /> at concentrations generally exceeding 1 part per million (ppm). In petroleum hydrocarbon affected <br /> i <br /> environments, the rate at which oxygen is replenished to the subsurface matrix by diffusion is dependent <br /> on soil porosity, permeability, and carbon percentage and may be inhibited by high concentrations of <br /> petroleum hydrocarbon constituents. <br /> Anaerobic biodegradation occurs when the subsurface matrix is oxygen deficient (DO levels generally <br /> • less than 1 ppm). In the event of oxygen deficiency, the microorganisms will utilize iron, sulfates, or <br /> nitrates as the mechanism for petroleum hydrocarbon breakdown. Anaerobic biodegradation typically <br /> is 10 to several hundred times less effective than aerobic biodegradation (EPA 510-B-94-003, 1994). <br /> To evaluate the aerobic/anaerobic conditions at the subject site, Delta collected DO measurements from <br /> monitoring wells MW-3 through MW-6 on May 5, 1995, utilizing a down-hole direct-reading DO meter. <br /> Dissolved oxygen measurements collected in monitoring wells MW-3, MW-4, MW-5 and MW-5 reported <br /> concentrations of 7.6, 1.9, 1.3, and 5.9 ppm, respectively. Each of the DO readings collected from the <br /> four wells exceeded 1 ppm, indicating a sufficient supply of oxygen for aerobic biodegradation of any <br /> remaining petroleum hydrocarbon constituents. <br /> 7.0 RATIONALE FOR CLOSURE <br /> Based on information collected to date, soil containing residual petroleum hydrocarbons is present in <br /> limited areas at the site. Concentrations of TPH as gasoline and BTEX have been below the laboratory's <br /> detection limits in all ground water monitoring wells for four consecutive quarters. During this time, <br /> . ground water has fluctuated approximately four feet and has been at a site historical high level. The total <br /> RPT001.810 <br />