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L <br /> L <br /> During its early period of record(1994-2001),nitrate concentrations in samples retrieved from the <br /> L Brown's New well were stable, fluctuating between 6 and I 1 mg/L; and its recent samples are within that <br /> range or lower. Nitrate concentrations in the Granite#3 and Granite#4 range from 6.5 to 16 mg/L. <br /> L The greatest long-term variability and seasonal variability is exhibited by the Brown's#1 well. Nitrate <br /> concentrations initially increased from 12 to 30 mg/L in 1994,decreased to 12-16 mg/L in 1997-98,and <br /> since then increased to 48.5 mg/L(May 2004). Since nitrate concentrations began increasing in 1999, <br /> seasonal fluctuations also increased. <br /> LThe presence of the observed nitrate concentrations is likely related to both the historical agricultural land <br /> use in the area prior to the commencement of aggregate mining by Teichert Aggregates and also <br /> Lcontinuing farming practices. This includes the nitrate concentration increases in the Brown's#1 well. <br /> Copper,iron,and zinc concentrations in shallow groundwater samples are typically low and frequently <br /> L below their respective reporting limits. For example, the record(73 monitoring events)for the Hall well <br /> shows two copper detection(100 µg/L in May 1999 sample and 20 Itg(L in November 2013 ),five iron <br /> detections(50 to 100 µg/L),and six zinc detections(30 to 130 µg/L). To date,manganese has not been <br /> detected in the Hall well. In samples retrieved from the Faulkner well,copper and manganese <br /> L concentrations have always been nondetect;iron and zinc concentrations have ranged from<10 to 210 <br /> µg/L and from<20 to 220 µg/L,respectively. <br /> L As in shallow groundwater samples,traces of copper concentrations in most deep groundwater samples <br /> are rarely detected. In contrast,iron,manganese and zinc are frequently detected in most deep wells; and <br /> variability is high. Most frequently,these metals were detected in samples retrieved from the Brown's <br /> L New well and the Brown's#1 well. These metals are also present in well water more recently retrieved <br /> from the Granite#3 well. Metal detections in the South Tracy#1 and#3 wells are few. <br /> Total coliform bacteria have been nondetect from the Hall and Faulkner domestic wells with few <br /> L exceptions. Most recently,total coliform bacteria were detected at the reporting limit of 1.1 MPN/100 <br /> mL in the August 2008 sample retrieved from the Hall well. Fecal coliform organisms were nondetect. <br /> The sporadic presence of coliform bacteria can be due to sample contamination at the time of collection, <br /> L the introduction of coliform bacteria to the well structure during well and pump maintenance work,or the <br /> detachment of bacterial biofilm from the well structure in combination with naturally occurring coliform <br /> organisms. <br /> I- <br /> L <br /> I. <br /> L <br /> L <br /> L <br /> L ©WHDORFF&SC LMANINI <br /> on — n —1- 1E[— 7 <br /> L <br />