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i mum = , PAGE' 1 ti DATE( 12/02/92 ACCT: 241512-01 PAGE I �I DATE! 12/02192 ACCT: 241572-01 )E INDEX: 04523369190 CAT Not A4514 Pd NAR N/A iNDEX1 04923369190 CAT N01 A4324 PO MBR N/A d ":METHANOL"' DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT FLAME OR OXIDIZERS METHANOL:: VAPORS VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE I METHANOL OF IGNITION AND FLASH BACK MATERIAL SAFETY DATA SHEET VAPOR AIR MIXTURES ARE EXPLOSIVE FLASH POINT 51 F III C)ICC) UPPER EXPLOSIVE LIMIT 360% FISHER SCIENTIFIC EMERGENCY NUMBER [201] 796 7100 I CHEMICAL DIVISION CHEMTREC ASSISTANCE ( 00)424 9300 1 REAGENT LANE LOWER EXPLOSIVE LIMIT 601 AUTOIGNITtON TEMP 725 F(365 CI I FAIR LAWN NJ 07410 (201) 796-7100 FLAMMABILITY CLASS`OSHA) 18 THIS INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST FIREFIGHTING MEDIA INFORMATION CURRENTLY AVAILABLE TO US HOWEVER WE WAKE NO WARRANTY OF DAT CHEMICAL, CARBON DIOXIDE WATER SPRAY OR ALCOHOL RESISTANT FOAM MERCHANTABILITY OR ANY OTHER WARRANTY EXPRESS OR IMPLIED WITH RESPECT TO 11990 EMERGENCY RESPONSE GUIDEBOOK DOT P 560051 SUCH INFORMATION AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE USERS SHOULO MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE FOR LARGER FIRES USE WATER SPRAY FOG OR ALCOHOL RESISTANT FOAM INFORMATION FOR THEIR PARTICULAR PURPOSES 11990 EMERGENCY RESPONSE GUIDEBOOK DOT P 5800 51 FIREFIGHTING SUBSTANCE IDENTIFICATION MOVE CONTAINER FROM FIRE AREA IF YOU CAN 00 IT WITHOUT RISK DIKE FIRE CONTROL WATER FOR LATER DISPOSAL DO NOT SCATTER THE MATERIAL APPLY COOLING WATER TO CAS NUMBER 67 56 I SIDES OF CONTAINERS THAT ARE EXPOSED TO FLAMES UNTIL WELL AFTER FIRE IS OUT SUBSTANCE "METHANOL*' STAY AWAY FROM ENDS OF TANKS WITHDRAW IMMEDIATELY IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICE OR ANY DISCOLORATION OF TANK DUE TO FIRE ISOLATE TRADE NAMES/SYNONYMS FOR 112 MILE IN ALL DIRECTIONS IF TANK RAIL CAR OR TANK TRUCK IS INVOLVED IN METHYL ALCOHOL WOOD ALCOHOL METHYL HYDROXIDE CARBINOL FIRE 11990 EMERGENCY RESPONSE GUIDEBOOK DOT P 5800 5 GUIDE PAGE 181 it MONOHYDROXYMfTHANE WOOD SOIRIT WOOD NAPHTHA METHYLOL COLONIAL SPIRIT COLUMBIAN SPIRIT PYROkYLIC SPIRIT COULOMATIC(R CbNOITIONER SOLUTION EXTINGUISH ONLY IF FLOW CAN BE STOPPED USE WATER IN FLOODING AMOUNTS AS FOG STANDARD WATER IN METHANOL STCC 4909230 UN 1 30 RCRA U154 SOLID STREAMS MAY NOT BE EFFECTIVE COOL CONTAINERS WITH FLOODING QUANTITIES A454 A452 A935 A4G8 A947 A935 BP1105 A412 A411 A433P SW2 OF WATER APPLY FROM AS FAR A DISTANCE AS POSSIBLE AVOID BREATHING TOXIC SC95 A452�K A4D8SK A412P A434 441 2S A450 A433S CH40 ACC14280 VAPORS KEEP UPWIND r CHEMICAL FAMILY TRANSPORTATION DATA HYDROXYL ALIPHATIC MOLECULAR FORMULA C-H3-0 H DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION 49 CFR 172 101 FLAMMABLE LIQUID MOLECULAR WEIGHT 32 04 DEPARTMENT Of TRANSPORTATION LABELING REQUIREMENTS 49 CFI( 171 101 AND CERCLA RATINGS (SCALE 0 3) HEALTH-3 FIRE-3 REACTIVITY 0 PERSISTENCE 0 SUBPART E NFPA RATINGS (SCALE 0 4) HEALTH-1 FIRE-3 REACTIVITY-0 FLAMMABLE LIQUID --------- -- - q COMPDNENTS AND CONTAMINANT$ DEPARTMENT OF TRANSPORTATION PACKAGING REQUIREMENTS 19 CFR 173 119 EXCEPTIONS 49 CFR 173116 COMPONENT METHYL ALCOHOL(METHANOL) PERCENT 100 I CASN 67_56_1 FINAL RULE B HAZARDOUS MATERIALS REGULATIONS `HMR 49 CFA PARTS 171 1601 DOCKET NUMBERS HM 161 HM 161A HM 1818 HM 16 C HM 1810 AND HM 204 OTHER CONTAMINANTS NONE EFFECTIVE DATE OCTOBER 1 1991 HOWEVER COMPLIANCE WITH THE REGULATIONS 15 AUTHOR12ED ON AND AFTE0 JANUARY 1 1991 (55 FA 52402 12/11/901 If EXPOSURE LIMITS EXCEPT FOR EXPLOSIVES INHALATION HAZARDS AND INFECTIOUS SUBSTANCES THE METHYL PPM L2B2 MG!M3 OSHA A{SKIN! 2150 PPM(328 MG/M3``OSHA STEL EFFECTIVE DATE FOR HAlARD COMMUNICATION REQUIREMENTS IS EXTENDED TO 200 PPM 252 MG/M3 ACGIH TWA++S KIN; 250 PPM 326 MG/M3)ACGIH STEL OCTOBER 1 1993 156 FR 47158 09116/91) 200 PPM Ib2 MG/M3 NIOSH RECOMMENDED TWA SKIN) U S DEPARTMENT OF TRANSPORTATION SHIPPING NAME I❑ NUMBER 49 CFR 172 101 250 PPM 328 MG/M3 NIOSH RECOMMENDED STEL METHYL ALCOHOL UN 1230 200 PPM 262 MG/M3 DFG MAK TWA{SKIN) 400 PPM 524 MG/M3 DFG MAK 30 MINUTE PEAK AVERAGE VALUE 4 TIMES/SHIFT U$ DEPARTMENT Of TRANSPORTATION HAZARD CLASS OR DIVISION 49 CFR 172 101 MEASUREMENT DETECTION VOL III Y 2 OpWATER R GAS CHROMATOGRAPHY WITH FLAME 3 - FLAMMABLE LIQUID U S DEPARTMENT OF TRANSPORTATION PACKING GROUP 49 CFR 172 101 5000 POUNDS CERCLA SECTION 103 REPORTABLE QUANTITY PG II SUBJECT TO SARA SECTION 313 ANNUAL TOXIC CHEMICAL RELEASE REPORTING r UAND SU9PApTNE OF TRANSPORTATION LABELING REQUIREMENTS 49 CFR 172 iQi •1�TH C RCUIT COURT OF APPEALS(AFl1 G80 VROSMAj AS OFCT OJULY DECISION OF THE FLAMMABLE LIQUID POISON U S DEPARTMENT OF TRANSPORTATION PACKAGING AUTHORIZATIONS II PHYSICAL DATA EXCEPTIONS NONE NON BULK PACKAGING 49 CFR 173 202 DESCRIPTION CLEAR COLORLESS LIQUID WITH A CHARACTERISTIC ALCOHOLIC ODOR BULK PACKAGING 49 CFR 173 243 + 801LING POINT 149 F 165 C) MELTING POINT -137 F( 94 C) US DEPARTMENT OF TRANSPORTATION QUANTITY LIMITATIONS 49 CFR 172 101 PASSENGER AIRCRAFT OR RAILCAR I L SPECIFIC GRAVITY (1 7914 VAPOR PRESSURE 97 25 MMHG CA 20 C CARGO AIRCRAFT ONLY 60 L l EVAPORATION RATE (BUTYL ACETATE-1)4 6 SOLUBILITY IN WATER VERY SOLUBLE TOXICITY r ODOR THRESHOLD 100 PPM VAPOR DENSITY 1 11 METHYL ALCOHOL IMETHANQLI SIRRITATION DATA 220 MG/24 HOURS SKIN RABBIT MODERATE 40 MG EYE RABBIT SOLVENT SOLUBILITY ETHER BENZENE ALCOHOL ACETONE CHLOROFORM ETHANOL y MODERATE 100 MG/24 HOURS EYE RABBIT MODERATE VISCOSITY p 54 CPS @ 20 C TOXICITY DATA 66 000 MG/M3 INHALATION HUMAN TCLO 300 PPM INHALATION HUMAN TCLO 64 000 PPM/4 HOURS INHALATION RAT LC50 1000 PPM INHALATION MONKEY ` LCLO 50 GM�M3/2 HOURS INHALATION MOUSE tClO 44 000 MG/M316 HOURS FIRE AND EXPLOSION DATA INHALATION CAT LCLO 15800 MG/KG SKIN RABBIT LD50 393 MG1KG SKIN MONKEY LDIO 42B MG/KG ORAL HUMAN LOLO 143 TAG KG ORAIFMVAAN LOlt7 6422 MG/KG Clnr r rr nr nr ^ r rr � ^ 1 n rh rF