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Fernando's Place - 2 - 29 September 2016' <br /> 1201 South Center Street <br /> Stockton, San Joaquin County <br /> Boring CPT-15 (2007), the farthest sampling location to the east (approximately 430 <br /> feet), contained benzene concentrations of 69 ug/L in HU1 Upper, 27 ug/L in HU1, <br /> 650 ug/L in HU3, and 500 ug/L in HUS. Boring CPT-13 (2007), approximately 40 feet <br /> north of the Site, contained benzene concentrations of 71 ug/L in HU1 Upper, 11 ug/L in <br /> HU1 Lower, 22 ug/L in HU2, and 25 ug/L at 184 feet bgs (between HU4 and HU5). <br /> Depth discrete groundwater sampling in boring CPT-4 (2001), located approximately 60 <br /> feet southwest of the Site across French Camp Road, indicated the presence of <br /> benzene above the WQO as deep as HU3 (68 ug/L), and a maximum benzene <br /> concentration of 7,300 ug/L in HU1 Upper. These data indicate that additional lateral <br /> and vertical delineation is needed to the north, northeast, east, and southeast of the Site. <br /> By 30 November 2016, please submit a Work Plan which includes a proposal for the <br /> collection of a sufficient number of groundwater samples to adequately delineate <br /> groundwater pollution to the WQOs laterally and vertically to the north, northeast, east, <br /> and southeast of the Site. <br /> 2. The Central Valley Water Board permits and regulates the injection of oxidizers into the <br /> subsurface such as ozone or in-situ chemical oxidants (ICSO) like peroxide under Order <br /> No. R5-2015-0012, Waste Discharge Requirements General Order for In-Situ <br /> Groundwater Remediation and Discharge of Treated Groundwater to Land(General <br /> Order). It appears that prior to the ozone injection pilot test that was conducted at the <br /> Site between 11 November 2013 and 2 October 2014, a Notice of Intent (NO]) <br /> application for permit under the General Order was not submitted to the Central Valley <br /> Water Board, nor was a Notice of Applicability (NOA) issued by the Central Valley Water <br /> Board. Any further injection of oxidants at the Site must be permitted by the Central <br /> Valley Water Board. <br /> In the 4Q15 Report, AGE recommends a continuation of the ozone injection pilot test as <br /> well as an ISCO pilot test using hydrogen peroxide. Based on data presented in the <br /> Pilot Test Report, it does not appear that ozone injection has been effective at reducing <br /> groundwater contamination at the Site. Shallow screened (36-40 feet bgs) ozone wells <br /> OZ-4 through OZ-8 were located on the southeast corner of the property near <br /> groundwater monitoring wells MW-1 and MW-5, and intermediate screened (66-70 feet <br /> bgs) ozone wells OZ-1 through OZ-3 were located in the northeast corner near <br /> groundwater monitoring wells MW-3 and MW-4. While decreases in total petroleum <br /> hydrocarbons as gasoline (TPHg) and benzene concentrations were observed in shallow <br /> monitoring well MW-5A over the course of the pilot test, the application of ozone does <br /> not appear to have accelerated the decreasing trend in this well that began several <br /> years prior to the implementation of ozone. <br /> Also, concentrations in MW-1 fluctuated over the course of the pilot test, and cannot be <br /> described as decreasing when compared to the historical pattern of the monitoring data. <br /> Additionally, both MW-1 and MW-5A demonstrated significant increases in TPHg and <br /> benzene concentrations subsequent to the completion of the pilot test, which for some <br /> constituents were much higher than concentrations before ozone was implemented. <br /> In the Pilot Test Report, reductions in TPHg and benzene concentrations in wells <br /> MW-3A and MW-313 were used as evidence of effectiveness for the intermediate depth <br />