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• the building (JLM-9-29' and JLM-10-30') All five of the water-table samples that were <br /> tested for TPH as diesel exceeded the detection limit, and those concentrations were <br /> higher than the gasoline concentration in four of the five samples Whether diesel is <br /> actually present however, is uncertain, because the detected hydrocarbons span the <br /> transition from gasoline to kerosene to diesel and the laboratory noted that the samples <br /> may represent aged (weathered) gasoline <br /> Most samples contained no detectable concentrations of BTEX compounds, which <br /> testifies to the weathered nature of the gasoline Toluene was detected at 12 and 0 83 <br /> µg/l in the two samples below the building, and one of these also contained ethylbenzene <br /> and xylene at concentrations of 1 7 and 0 06 µg/1 Other gasoline compounds that were <br /> detected included three oxygenates (MTBE, DIPE, and TBA) and the lead scavenger 1,2- <br /> DCA Concentrations of these compounds were also low, mostly near 1 pg/l but ranging <br /> up to 24 µg/l for 1,2-DCA in JLM-9 <br /> The laboratory also detected hydrocarbons in the two samples that were collected from <br /> the lower portion of the first aquifer A TPH-g concentration of 77 µg/1 was detected in <br /> JLM-6-36', and a TPH-d concentration of 84 µg/1 was detected in JLM-11-38' No <br /> BTEX compounds were detected in either sample, but 1,2-DCA and MTBE were <br /> detected in both and DIPE was detected in JLM-11-38' The presence of these gasoline <br /> compounds suggests that the hydrocarbons reported as TPH-d may again represent <br /> weathered gasoline It is also worth noting that even though the sum of gasoline <br /> compounds detected in JLM-11-3 8' by EPA method 8260 exceeds the 50 µg/1 detection <br /> i limit for TPH-g (55 pg/l [1,2-DCA] +28 µg/l [DIPE] + 4 8 µg/l {MTBE] = 85 8 µg/l), <br /> the laboratory did not detect TPH-g above this limit using EPA method 8015 The fact <br /> that this sum is within 2 µg/1 of the reported TPH-d concentration further suggests that all <br /> of the reported TPH-d actually consists of lead scavengers and gasoline oxygenates rather <br /> than diesel fuel In addition, the fact that the 1,2-DCA concentration exceeded the MTBE <br /> concentration in most samples further suggests that the gasoline is old <br /> Figures 5-8 illustrate the distribution of gasoline-range hydrocarbons in groundwater as <br /> interpreted from the available samples These maps include older data from JLM-1 and <br /> JLM-2, as well as the most recent (January 2003) data from JLM-4 through JLM-6, so <br /> they do not represent a single monitoring event, but rather a general picture of the <br /> impacted area The maps for TPH-g, total oxygenates, and 1,2-DCA are all quite similar, <br /> and depict an elliptical contaminant plume that trends generally northwest-southeast The <br /> plume is quite similar iri shape to the shape of the impacted soil (Figure 4), although the <br /> groundwater impact is more extensive BTEX compounds appear to be more uniformly <br /> distributed in the groundwater, although there is a slight north-south elongation as <br /> presently mapped The groundwater plume appears to originate between JLM-5 and the <br /> former tank cavity and become wider to the southeast, parallel to the groundwater flow <br /> direction that has been observed during the past three calendar quarters This suggests <br /> downgradient dispersion of petroleum molecules <br /> As discussed above, the laboratory detected extractable hydrocarbons in six samples <br /> using the EPA method 8015/3550 method and reported them as TPH-d These <br /> 6 <br />