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Oil Exploration and Production Wastes Initiative Anal ses .Performed - <br />The E&P waste samples collected were analyzed under the following parameters <br />of study: pH; flash point; aquatic toxicity; metals; volatile organic compounds <br />(VOCs); semi -volatile organic compounds (SVOCs); benzene; toluene; xylene <br />(BTX); and total petroleum hydrocarbons (TPH). <br />The number of samples analyzed was not the same for all tests. For example, <br />the aquatic toxicity bioassay was conducted on one sample per wastestream, per <br />facility. The number of sampled analyzed for VOCs and SVOCs was also <br />smaller due to financial limitations, but was sufficient to support interpretive <br />conclusions. <br />Table 6 is a complete listing of all parameters of analysis, the number of samples <br />analyzed for each wastestream, parameters of study, and number and <br />percentages of samples with values below detection limits, where detection limits <br />are applicable. Because each wastestream displayed variation in the type of <br />analytes detected, subsequent tables list only detected analytes for the <br />wastestreams presented. <br />Tables 7, 9, 11, and 13 summarize results obtained for produced water, drilling <br />waste, oily sludge, and foam treatment waste, respectively. The statistical <br />calculations included for each parameter are mean, median, standard deviation, <br />and percentages of samples with values above the regulatory threshold (RT), <br />where RTs are applicable. The following approach was used for statistical <br />calculations involving the data. <br />For some tests (e.g., VOCs), the values obtained were below detection limits, or <br />not detected (ND). According to standard DTSC procedure, for purposes of <br />statistical calculations ND values are typically replaced with half the value of the <br />detection limit (DL). This procedure assumes that if a contaminant was not <br />detected, it is present in the sample at a concentration that is equal to half the <br />lowest detectable concentration. Given the fact that DL is not a constant for each <br />test but varies with the matrix for each individual sample, SCD chose to forgo the <br />above procedure for practical reasons, and assume a value of 0 for all ND <br />values. This method theoretically introduces a bias in the data in favor of the <br />generator, by assuming that if a contaminant was not detected, is was not <br />present in the sample in any concentration. However, for purposes of this project, <br />it was determined that using 0 in lieu of half DL in statistical calculations would <br />not affect the outcome of the study, because the concentration of the detected <br />analytes in those samples was far below RT. <br />It was noted that the data obtained from some analyses did not display a normal <br />distribution, as indicated by the fact that the mean value was lower than the <br />Statewide Compliance Division Ma 2002 <br />-17- <br />