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' r <br /> , <br /> 28 February 1997 <br />'16 AGE-NC Project No 95-0144 <br /> Page b of 20 <br /> 1 f ` <br /> In a carbon canister system, hydrocarbon vapor is routed through activated carbon filters where <br /> ' adsorption of hydrocarbons onto carbon takes place, removing the hydrocarbons from the vapor a <br /> stream This type of system works best for low concentrations of hydrocarbons, but becomes <br /> expensive when high concentrations of hydrocarbon vapors necessitate frequent canister replacement <br /> and disposal of spent carbon r <br /> ' Thermal oxidation' systems destroy hydrocarbons by open-flame combustion Natural gas is <br /> commonly used as supplemental fuel, heating the extracted vapor stream to a combustion <br /> temperature of approximately 1400°F Relative to internal combustion systems, these systems may <br /> be slightly more expensive to'purchase and install However, they can operate at higher air flow <br /> ' rates, and therefore remediate sites at a faster rate For this system to be effective, hydrocarbon <br /> concentrations should range from 5,000 ppmv to 30,000 ppmv Thermal oxidation systems operate <br /> ' at much lower noise levels than internal combustion systems u <br /> , <br /> Catalytic oxidation units provide another option for treating vadose-zone contamination,particularly <br /> ' after other extraction systems have reached their effective limits due to lowered hydrocarbon <br /> concentrations These systems operate at temperatures of approximately 700°F, requiring less <br /> supplemental fuel than either thenal oxidizers or internal combustion engines Other requirements <br /> and limitations are similar to those for internal-combustion and thermal oxidizer systems <br /> ' 5 1 2 REQUIRED SOIL CONDITIONS <br /> ' Operation_of the blower in a vapor extraction system creates a partial vacuum in the subsurface, <br /> inducing`air"currents"through the soil pore spaces Vapors move by convection toward the area of <br /> lowered air pressure (the extraction point) The efficiency of this process is proportional to soil <br /> ' porosity and permeability Qualitative information has been gained through the examination of soil ; <br /> 'samples collected at the site Soil in the upper 19 feet has a relatively'high clay and silt content, <br /> potentially making vapor extraction less effective for this zone Soil below 19 feet and in the , <br /> saturated zone consists of sand, rendering vapor extraction as an effective remediation method <br /> However, due to a recent rise in ground water at the site,this zone is below the current ground water <br /> table Figures 3 and 4 depict cross sections, showing subsurface soil types at the site <br /> 5 l 3 MONITORING ACTIVITIES <br /> Monitoring of vapor extraction systems involves weekly measurement of vapor concentrations at <br /> ' the inlet to the destruction unit and periodic service and repair Systems can be equipped with an <br /> automatic telecommunication system to alert the operator of system malfunction or failure Vapor <br /> samples should be collected monthly for laboratory analysis to monitor the efficiency of the <br /> r <br />