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'7 <br /> • APPENDIX 1 <br /> Groundwater Monitoring Procedures <br /> 10 GROUNDWATER SAMPLING PROTOCOL <br /> All equipment that is used in a monitoring well for purging,sampling or depth measurement shall be decontaminated <br /> by steam cleaning or a TSP wash and triple-rinse procedure prior to use and before reusing when purging or <br /> sampling <br /> 1 Each monitoring well is opened and allowed to equalize to atmospheric pressure prior to to <br /> sounding This time will be approximately %z hour Each well will be accessed and the wellhead checked <br /> for damage and tampering <br /> 2 The first well to be monitored will be known or suspected clean wells The next wells to be monitored will <br /> be known or suspected wells that will contain contaminated groundwater The furthest up gradient <br /> contaminated well will be monitored first Subsequent wells will be monitored on a down-gradient basis <br /> 3 The depth-to-groundwater will be measured from the predetermined measure point on the well casing with a <br /> sounding tape and recorded to the nearest 0 01 foot In most cases the measuring point is the survey mark <br /> on the top of the well casing The time,day and other observations will be recorded in a notebook The tip <br /> of the probe will then be examined in order to determine the presence or absence of product sheen If a <br /> product sheen is detected or the well is known to have been previously identified as having petroleum <br /> hydrocarbon contaminated groundwater then prior to purging, a clean,transparent bailer is lowered into the <br /> well,and a sample of groundwater is hoisted to the surface The sample fluid is inspected for the presence <br /> of free-floating product on its surface <br /> • 4 The depth probe is then weighted and the bottom of the monitoring well is determined and recorded <br /> A calculation of the water contained in a single well casing volume will be made <br /> 5 Sampling activities conducted subsequent to the initial water level and free-product layer determination will <br /> be preceded by purging a minimum of three to five well-volumes by hand-bailing or the use of an <br /> electrically-operated pump If a pump is used,the pump will be placed in the wellbore no more than five <br /> feet below the groundwater surface and the purging rate will be controlled so as to not allow the <br /> groundwater surface to decline more than two feet from the initial measurement These restrictions are to <br /> ensure that waters coming into the wellbore are representative in chemistry from the surrounding aquifer <br /> and are being extracted from the approximate depth of the groundwater surface and not from cascading <br /> water entering the wellbore filterpack from depths significantly below the top of the groundwater surface <br /> A well is allowed to recharge to at least 80%of its prepurge groundwater surface elevation prior to <br /> sampling The purging rate will not be so great as to cause the well to go dry or have the formation water <br /> cascade down the casing If purging causes the well to be pumped dry,it will be allowed to recharge for up <br /> to 24 hours prior to sampling If the well does not recharge within 24 hours,it will be considered to be a dry <br /> well <br /> 6 Purge water will be monitored for the parameters of temperature,pH,and electrical conductivity until <br /> stabilized The groundwater temperature,pH and electrical conductivity will be measured with field <br /> instruments and recorded in a notebook If required by regulatory agencies, field readings for dissolved <br /> oxygen(d-02), displayed to the nearest tenths of parts per million,will be obtained utilizing a YSI Model <br /> 50B or Hanna Instruments hand-held, HI-9142,Portable Dissolved Oxygen Meter or an equivalent device <br /> Generally, (d-OZ) higher concentrations are expected in samples which exhibit no impaction or are <br /> marginally impacted by hydrocarbons than for samples collected from monitoring wells which yield <br /> hydrocarbon-impacted water <br /> Maln\D\.nvironmenta[\ParmarTexaco\Reports\041403QMR wpd <br />