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(1 ) Sample collection; <br /> (2) Sample preservation and shipment; <br /> (3) Analytical procedures; and <br /> (4) Chain of custody control . <br /> (b) The owner or operator shall determine the concentration or value <br /> of the following parameters in ground-water samples in accord- <br /> ance with Item 2 (c) and (d) : <br /> (1 ) Parameters characterizing the suitability of the ground <br /> water as a drinking water supply as specified by EPA <br /> in Appendix III , Part 265, Title 40, Code of Federal <br /> Regulations. <br /> (2) Parameters establishing ground-water quality: <br /> (i ) Chloride <br /> (ii ) Iron <br /> (iii ) Manganese <br /> (iv) Phenols <br /> (v) Sodium <br /> NO Sulfate <br /> (3) Parameters used as indicators of ground-water contamination : <br /> (i ) pH <br /> (ii ) Specific Conductance <br /> (iii ) Total Organic Carbon <br /> (iv) Total Organic Halogen <br /> (c) (1 ) For all monitoring wells , the owner or operator shall <br /> establish initial background concentrations or values of <br /> all parameters specified in Item 2 Cb) . This shall be done <br /> quarterly for one year. <br /> (2) For each of the indicator parameters specified in Item 2 <br /> (b) (3) , at least four replicate measurements shall be <br /> obtained for each sample and the initial background <br /> arithmetic mean and variance shall be determined by pooling <br /> the replicate measurements for the respective parameter <br /> concentrations or values in samples obtained from upgradient <br /> wells during the first year. <br /> (d) After the first year, all monitoring wells shall be sampled and <br /> the samples analyzed with the following frequencies : <br /> (1 ) Samples collected to establish ground-water quality shall be <br /> obtained and analyzed for the parameters specified in <br /> Item 2(b) (2) at least annually. <br /> (2) Samples collected to indicate ground-water contamination <br /> shall be obtained and analyzed for the parameters specified <br /> in Item 2(b) (3) at least semi-annually. <br />