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�I <br /> 19 October 2012 <br /> AGE-NC Project No. 97-0312 <br /> Page 13 of 22 <br /> concentrations as high as 520 mg/kg and 32,000 mg/kg, respectively, in a sample collected <br /> approximately 2 feet below the east end of UST No.3 and at concentrations of 1,000 mg/kg <br /> and 11,000 mg/kg, respectively, in a sample collected at approximately 17 feet bsg below <br /> the UST No. 6 excavation. TPH-g and TPH-d were detected in piping/dispenser samples <br /> 6-0 at concentrations as high as 1,200 mg/kg and 16,000 mg/kg, respectively; BTEX <br /> constituents were detected at concentrations as high as 60 mg/kg (xylenes). <br /> h <br /> Once released to the subsurface, the contaminants migrated through the fine-grained silty <br /> material below the UST areas, to a vertical depth of approximately 20 to 30 feet bsg at the �`� <br /> northeastern UST location (UST Nos. 1 through 5), and to depths of 70 to 75 feet bsg west <br /> of the former UST No. 6 location. Contamination in the area of former UST Nos. 1 through <br /> 5 does not appear to extend below 40 feet bsg; petroleum hydrocarbons were not detected <br /> in soil samples collected below 30 feet bsg from soil boring B14. West of the former UST <br /> No. 6 area, vertical migration of TPH-g and BTEX contaminants appears to extend to <br /> depths as great as approximately 70 feet to 75 feet bsg. In a soil sample collected from <br /> boring MW-1 at 70 feet bsg, TPH-g and TPH-d were detected at concentrations of <br /> 5.3 mg/kg and 80 mg/kg, respectively; however, no petroleum hydrocarbon constituents <br /> were detected in a sample collected at 85 feet bsg from the same boring. Low detections r <br /> of TPH-g and BTEX were reported in soil samples collected from boring MW-9 at depths <br /> of 90 feet and 100 feet bsg; however, no petroleum hydrocarbon contamination has been <br /> reported in groundwater samples collected from the well to date. <br /> Currently, the Alaral extent of ads rbed petroleum hydrocarbon contamination is defined <br /> to the northeay boring MW-3, to the northwest by borings B4 and B25, to the west by <br /> boring MW-2, d to the south by borings B29, B22, and MW-4. The soil data lacks <br /> significant detections of 1,2-DCA in the most recent data, possibly demonstrating the <br /> vertical migration of this contaminant through soil without substantial attenuation or k41t <br /> adsorption to soil. The adsorbed petroleum hydrocarbon contamination appears to be C'° its <br /> adhered to fine-grained soil, based on the reduction of dissolved hydrocarbon �a " <br /> contamination with upward fluctuations of the groundwater table. �' <br /> 1-0 <br /> 5.2. IMPACT TO GROUNDWATER <br /> Significant concentrations of TPH-g, TPH-d, BTEX, and MTBE were detected in grab <br /> groundwater samples collected at 65 feet bsg in soil borings B14, B15, and B17. <br /> Historically, TPH-g has been detected in the on-site groundwater monitoring wells at a <br /> maximum concentration of 3,400 pg/I (MW-1, December 1992); TPH-g has been detected <br /> consistently only in well MW-5, with sporadic detections in wells MW-2 through MW-4; <br /> TPH-g was only detected in well MW-6 during its initial groundwater monitoring event in <br /> June 1999. TPH-d was detected at a maximum concentration of 350,000 pg/I in MW-1 in <br /> September 1992; TPH-d was detected consistently in MW-1 until the well was destroyed <br /> V <br /> Advanced GeoEnvironmental,Inc. <br /> v <br />