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S ECC R <br /> w�l } <br /> a <br /> vicinity of the subject site The well search was conducted within a '/Z-mile radius around the site <br /> Based on the available data supplied by the California Department of Water Resources (DWR), <br /> three municipal wells were identified within the '/-mile radius of the study area, the closest well is <br /> located approximately 1,000 feet north-northwest of the site The depths of all three municipal <br /> wells were reported to exceed 550 feet bgs and contain screened intervals beginning at a <br /> minimum of 350 feet bgs The SRS was conducted within a 500-foot radius centered around the <br /> subject site The SRS involved distributing questionnaires to all residences and businesses <br /> within the study area, requesting information about potential groundwater receptors GR <br /> distributed 141 questionnaires via the U S Post Office and a total of 49 questionnaires (35%) <br /> were returned to GR None of the returned questionnaires identified the presence of a well within <br /> the SRS study area (GR, 2001) <br /> MONITORING AND SAMPLING <br /> TRC's Groundwater Monitoring Report dated November 10, 2004 is included as Attachment A, <br /> including Tables 1- 3, Figures 1 - 6, plus field data sheets and groundwater analytical reports <br /> The site has been monitored and sampled since 2nd quarter, 1990 Between 1990 and 1991 the <br /> site was mon itoredlsampled semi-annually From 1992 to the present the Site has been <br /> monitored/sampled quarterly Currently MW-1 and MW-3 through MW-13 are monitored and <br /> sampled quarterly each year Samples are analyzed for TPHg, BTEX, and fuel oxygenates <br /> During the third quarter 2004 groundwater flow was toward the north at a gradient of 0 002 ft/ft <br /> Maximum reported concentrations of MtBE and TBA during the third quarter 2004 were 12 ppb <br /> (MW-4) and 83,000 ppb (MW-7), respectively Concentrations of MtBE, TPPH, and TBA continue <br /> to decline in site monitoring wells MtBE concentrations in wells MW-1, MW-3, MW-4, MW-5, <br /> MW-6, MW-7, MW-11, and MW-13 continue to decline (from a historical maximum of 233,000 <br /> • ppb to a current maximum of 12 ppb) TBA concentrations in wells MW-1, MW-3, and MW-7 <br /> continue to decline from a historical maximum of 240,000 ppb to a current maximum of 83,000 <br /> ppb TBA concentrations in well MW-11 have increase to a historical high during the third <br /> quarter Based on MtBE and TBA isoconcentration maps (Figures 5 and 6 in Attachment A), <br /> these constituents are not delineated to the northeast of the site (in the area of Shell well S-2) <br /> SECOR recommends that during joint sampling with Shell, ConocoPhdlfps' sampling contractor <br /> collect split samples from Shell wells S-2 and S-5 and analyze for fuel oxygenates to determine <br /> the delineation of MtBE and TSA <br /> REMEDATION STATUS <br /> The ozone injection system consists of a panel mounted KVA C-SpargeTM System that produces <br /> 4 grams per hour (0 009 pounds per hour) of ozone The system injects ozone to ten ozone wells <br /> SP-A through SP-H, SP-J, and SP-K The system was placed into operation on December 20, <br /> 2001 During the current quarter the system operated for 754 hours, resulting in 41% runtime <br /> The system was found to be non-operational on July 29 and August 18, 2004, due to the GFI <br /> being tripped It was restarted both times On September 20, 2004, the compressor piston was <br /> replaced, as it was fading Ozone injection system operational data is included as Table B-1 in <br /> Attachment B <br /> The performance of the ozone injection system is evaluated based on the results of regular <br /> groundwater sampling Monthly groundwater samples were collected from monitoring wells MW-3 <br /> and MW-4 on July 29, August 19, and September 16, 2004, and analyzed for total petroleum <br /> hydrocarbons as gasoline (TPHg), benzene, toluene, ethylbenzene, and total xylenes (BTEX <br /> compounds), methyl tert-butyl ether (MtBE), and tert-butyl alcohol (TBA) Monthly sampling of <br /> wells MW-3 and MW-4 indicate that ozone sparging continues to be effective in reducing <br /> concentrations of dissolved petroleum hydrocarbons Results of monthly groundwater sampling <br /> events are summarized in Table B-2 Concentration versus time graphs for dissolved TPHg, <br /> benzene, MtBE, and TBA in monitoring wells MW-3 and MW-4 are provided in Figures B-1 and B- <br /> t <br />