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ARCHIVED REPORTS XR0006135
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3500 - Local Oversight Program
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PR0544590
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ARCHIVED REPORTS XR0006135
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Last modified
6/21/2019 4:04:15 PM
Creation date
6/21/2019 11:17:54 AM
Metadata
Fields
Template:
EHD - Public
ProgramCode
3500 - Local Oversight Program
File Section
ARCHIVED REPORTS
FileName_PostFix
XR0006135
RECORD_ID
PR0544590
PE
3528
FACILITY_ID
FA0003932
FACILITY_NAME
KWIKEE FOODS
STREET_NUMBER
2081
STREET_NAME
COUNTRY CLUB
STREET_TYPE
BLVD
City
STOCKTON
Zip
95204
APN
12315225
CURRENT_STATUS
02
SITE_LOCATION
2081 COUNTRY CLUB BLVD
P_LOCATION
99
P_DISTRICT
001
QC Status
Approved
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Similar results are obtained when samples are analyzed by both methods. As an example, the first <br /> time the MTBE concentration was analyzed both ways in MW-1, the laboratory reported 1,130 ppb <br /> by method 8020 but only,120 ppb by method 8260. Because of the inaccuracy of the 8020 data at <br /> both sites, the 8020 results were not used in constructing contour maps of the MTBE plurrie, <br /> although they are shown in parentheses in the reaps that follow. <br /> In section 4.5, clockwise rotation and southward or southeastward advection of the TPH-g plume <br /> were discussed. Figure 33 illustrates this further, using the MTBE data. Because only the Kwikee <br /> samples were analyzed by EPA method 8260 in December 2000, the map is strongly constrained <br /> only by the Kwikee data, but qualitatively comparing. the 8020 results for both sites over the <br /> previous several quarters suggests that MTBE concentrations have generally been higher in <br /> Chevron wells than in Kwikee.wells. Therefore, the core of the MTBE plume is mapped in Figure <br /> 32 west of the Kwikee site, but the apparent absence of MTBE in MW-2 and MW-3 suggests that <br /> the MTBE core was not located west of MW-1. Further qualitative evaluation of the rapid decrease <br /> in MTBE concentration between MW-1 and MW-2 suggests that the contours are tightly <br /> compressed between these wells, whereas quantitative evaluation of the data from KF-3 and KF-5 <br /> indicates that contours on the east end of the plume are spread farther apart. This is another <br /> example of longitudinal dispersion downgradient from the contaminant source, which further <br /> supports the view that the source was located west of the Kwikee site. However, due to the greater <br /> mobility of MTBE in groundwater, it is able to move en masse by advection more easily than other <br /> gasoline compounds, which would explain why the core of the MTBE plume appears to have <br /> moved east and south of MW-1 while the core of the TPH-g plume did not. <br /> • Figure 34 shows another snapshot of the MTBE plume, using data from February 2002. This map is <br /> constrained by EPA 8260 data from both sites, and it is evident that MTBE concentrations were <br /> nearly the same in MW-1, MW-6, and KF-3 at that time. This adds further support to the <br /> interpretation that the center of the plume was located between these three wells. Further, note that <br /> the MTBE concentration in MW-1, as determined by EPA method 8020, was approximately 200 <br /> ppb, and compare this value to that determined using the same method during the previous four <br /> quarters (<1,000 ppb, 1,130 ppb, 1,800 ppb, and 1,200 ppb). These data can be interpreted as <br /> indicating that the core of the MTBE plume was closer to MW-1 during those quarters than it was <br /> in the fourth quarter of 2001, or that MTBE concentrations declined during the fourth quarter. The <br /> decline from 53 ppb in December 2000 to 7.6 ppb in February 2002 in KF-5 supports the possibility <br /> of an overall concentration decrease, but the concentration in KF-3 was nearly unchanged, <br /> supporting the alternate possibility that the plume merely rotated clockwise farther and was oriented <br /> more northwest-southeast. Figure 34 incorporates both possibilities. The maximum concentration is <br /> shown decreasing from>125 ppb to just over 100 ppb and the concentration in MW-6 is interpreted <br /> to have decreased from about 125 ppb to 64 ppb. The plume has also been rotated about 5° <br /> clockwise (the same amount of rotation as was seen in the TPH-g plume in 2000). <br /> The MTBE plume had the same orientation in May 2002, but concentrations increased in all of the <br /> impacted wells and the plume evidently migrated eastward (Figure 35). This migration coincided <br /> perfectly with the strong eastward gradient (Figure 20)' that developed after the Chevron <br /> 20 <br />
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