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S E C O R <br /> 7-Eleven Store#14117 <br /> Field Test for Evaluation of Oxidation Capacity of Groundwater <br /> July 22, 2004 <br /> Page 3 <br /> On October 30, 2001, three groundwater monitoring wells (MW-5, MW-6, and MW-7) were <br /> advanced to 20 feet bgs TPHg, BTEX, and MtBE in soil were not detected above <br /> laboratory reporting limits, except for 0 006 mg/kg total xylenes (MW-7@20') (Table 1) <br /> Selected halocarbons also reported in the soil samples indicated possible dry cleaner <br /> plume contributions (IT Corporation, 1999) An active USA Gasoline (former Exxon) <br /> service station is located east of the site <br /> On August 14, 2003 SECOR oversaw the installation of one monitoring well (MW-8) and <br /> one soil boring (SB-1) (Figure 2) Soil samples collected from MW-8 indicated that the <br /> vertical limits of TPHg, benzene, and MtBE in soil have been defined south of the pump <br /> islands (Figure 2 and Table 1) The presence of benzene, TPHg, and MtBE in grab <br /> groundwater samples collected from MW-8 and SB-1 indicate that the vertical limit of <br /> dissolved hydrocarbons is not defined onsite south and east of the pump island (Table 2) <br /> On February 27, 2004 SECOR submitted the Additional Stte Assessment Report and Fate <br /> and Transport Model, which included the results of the August 2003 well installation and the <br /> results of Fate and Transport modeling using Flowpath 2 Historical groundwater flow <br /> direction data indicated a time-dependent variability in groundwater flow direction, which <br /> appeared to result in a net zero gradient over an extended period of time Four models <br /> were run with varying results Results of the first and second modeling runs were very <br /> similar and indicate that MtBE will mtgrate approximately 120 to 180 feet from the source <br /> area to the northeast Results of the third and fourth modeling runs represented a near- <br /> "flat" hydraulic gradient and indicated that the MtBE contamination would remain in the <br /> immediate vicinity of the UST area and concentrations will decrease with time due to <br /> dispersion and natural decay Overall, it was determined that it is difficult to accurately <br /> model the migration of contaminate plumes at this site because of the relatively flat <br /> groundwater table and the highly variable groundwater flow direction in the area <br /> OXYGEN INJECTION WELL INSTALLATION <br /> SECOR proposes the installation of one injection well that will be used to conduct oxygen <br /> injection (Figure 3) Oxygen injection is used to stimulate the biodegradation of gasoline- <br /> range petroleum hydrocarbons and oxygenates dissolved in groundwater Past studies on <br /> subsurface bacterial colonies (Site Conceptual Model, Shaw Group, June 20, 2002) <br /> indicate indigenous populations of bacteria are present in-situ at the site, and are capable <br /> of intrinsic biodegradation The injection well will be placed within five feet of MW-1 for use <br /> as an observation well within the radius of influence of oxygen injection <br /> Site Health and Safety <br /> As required by the Occupational Health and Safety Administration (OSHA) Standard <br /> "Hazardous Waste Operations and Emergency Response" guidelines (29 CFR 1910 120), <br /> and by California Occupational Health and Safety Administration (Cal-OSHA) "Hazardous <br /> Waste Operations and Emergency Response" guidelines (CCR Title 8, Section 5192), <br /> SECOR will prepare a Site-Specific Health and Safety Plan prior to the commencement of <br /> 14117 Field Test Oxidation Capacity doc SECOR international Incorporated <br />