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EE!rJa <br /> MATERIAL SAFETY DATA SHEET <br /> Diesel Fuel All Types) MSDs No. 9909 <br /> LARGE FIRES: Water spray,fog or fire fighting foam. Water may be ineffective for fighting the fire, but <br /> may be used to cool fire-exposed containers. <br /> FIRE FIGHTING INSTRUCTIONS <br /> Small fires in the incipient(beginning) stage may typically be extinguished using handheld portable fire <br /> extinguishers and other fire fighting equipment. <br /> Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of <br /> combustion should require NIOSH/MSHA-approved pressure-demand self-contained breathing <br /> apparatus with full facepiece and full protective clothing. <br /> Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire and <br /> excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may <br /> be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing <br /> the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to <br /> extinguish the fire, often including the need for properly applied fire fighting foam. <br /> See Section 16 for the NFPA 704 Hazard Rating. <br /> 6. ACCIDENTAL RELEASE MEASURES <br /> ACTIVATE FACILITY'S SPILL CONTINGENCY OR EMERGENCY RESPONSE PLAN. <br /> Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind direction; stay <br /> upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers, etc. to confirm spill <br /> areas. Spills may infiltrate subsurface soil and groundwater; professional assistance may be necessary <br /> to determine the extent of subsurface impact. <br /> Carefully contain and stop the source of the spill, if safe to do so. Protect bodies of water by diking, <br /> absorbents, or absorbent boom, if possible. Do not flush down sewer or drainage systems, unless <br /> system is designed and permitted to handle such material. The use of fire fighting foam may be useful in <br /> certain situations to reduce vapors. The proper use of water spray may effectively disperse product <br /> vapors or the liquid itself, preventing contact with ignition sources or areas/equipment that require <br /> protection. <br /> Take up with sand or other oil absorbing materials. Carefully shovel, scoop or sweep up into a waste <br /> container for reclamation or disposal -caution,flammable vapors may accumulate in closed containers. <br /> Response and clean-up crews must be properly trained and must utilize proper protective equipment <br /> (see Section 8). <br /> 7. HANDLING and STORAGE <br /> HANDLING PRECAUTIONS <br /> Handle as a combustible liquid. Keep away from heat, sparks, and open flame! Electrical equipment <br /> should be approved for classified area. Bond and ground containers during product transfer to reduce the <br /> possibility of static-initiated fire or explosion. <br /> Diesel fuel, and in particular low and ultra low sulfur diesel fuel, has the capability of accumulating a static <br /> electrical charge of sufficient energy to cause a fire/explosion in the presence of lower flashpoint products <br /> such as gasoline. The accumulation of such a static charge occurs as the diesel flows through pipelines, <br /> filters, nozzles and various work tasks such as tank/container filling, splash loading, tank cleaning; <br /> product sampling; tank gauging; cleaning, mixing, vacuum truck operations, switch loading, and product <br /> agitation. There is a greater potential for static charge accumulation in cold temperature, low humidity <br /> conditions. <br /> Documents such as 29 CFR OSHA 1910.106"Flammable and Combustible Liquids, NFPA 77 <br /> Recommended Practice on Static Electricity, API 2003"Protection Against Ignitions Arising Out of Static, <br /> Lightning, and Stray Currents and ASTM D4865"Standard Guide for Generation and Dissipation of Static <br /> Revision Date: 10/18/2006 Page 3 of 7 <br />