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DR A <br /> HAZARD EVALUATION <br /> TLV IDLH LEL <br /> Parameter (ppm) (ppm) (%) HEALTH <br /> gasoline 300 in air ND 1.4 eyes, skin,resp sys, CNS, liver,kidneys <br /> benzene 10 in air 500 1.2 eyes, skin, resp sys,blood, CNS,bone marrow <br /> toluene 100 in air 500 1.1 eyes, skin,resp sys, CNS, liver, kidneys <br /> ethylbenzene 100 in air S00 0.8 eyes, skin,resp sys, CNS <br /> xylenes 100 in air 900 0.9 - 1.1 eyes, skin,resp sys, CNS, GI tract, liver, kidneys <br /> MtBE/oxygenates 100 in air NIA LFL: 2.5 as above <br /> SPECIAL PRECAUTIONS: <br /> Remove PPE when wet or contaminated; prevent eye or skin contact; recommend access to eyewash <br /> and/or quick drench facilities. Respiratory protection not normally needed; ensure good ventilation. If <br /> breathing stops as result of sever inhalation, provide mouth-to-mouth cautiously using protection. <br /> FIRST AID: <br /> Contact (Skin and eyes): Remove contact lenses; irrigate eyes/flush skin with cold water immediately <br /> Inhalation: Move to fresh air immediately; provide mouth-to-mouth resuscitation if breathing stops <br /> Ingestion: Immediate medical attention required; drink several glasses water/milk, induce vomiting <br /> Other: <br /> IV. PERSONAL PROTECTIVE EQUIPMENT <br /> Minimum personal protective equipment, check all a licable items. <br /> ® Hard-hat Level of personal protection: <br /> ® Safety glasses/goggles/face shield <br /> ® Steel-toed/shank shoes or boots ❑ A <br /> ® Clothing protection/gloves ❑ B <br /> ® Hearing protection ❑ C <br /> ❑ Negative-pressure respirator ® D <br /> ® Safety vest <br /> ❑ Other(specify): <br /> SURVEILLANCE EQUIPMENT AND MATERIALS <br /> Instrument Action Level <br /> HNU PID Work in breathing zone will be suspended when <br /> hydrocarbon levels reach 25 ppm for 5 minutes. <br /> 911-011.1A/0102/SSP <br />