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Remedial Action Plan and Further Site Assessment 6 <br /> 7-Eleven Store No 19976 1399 N Main St Manteca CA May 30 2000 <br /> Equipment required for vapor extraction/air sparging Includes a positive-displacement blower or air <br /> compressor, in addition to equipment required for vapor extraction The treatment efficiency of air <br /> sparging as a remediation process is variable, with up to 90 - 95 percent reductions in dissolved levels <br /> (from initial concentrations)reported using this form of remediation There is as yet no well-established <br /> track record of this treatment method for MTBE, but pilot tests (ACS Convention,April 2000) demonstrate <br /> limited success in mass transfer of MTBE from the liquid to the vapor phase by conventional sparging <br /> Heated air sparging may likely prove more effective in overcoming the high solubility of MTBE, but safety <br /> issues regarding treatment of mobile flammable vapors such as gasoline would need to be addressed <br /> prior to application <br /> Carbon adsorption can be used to treat extracted soil vapors at an efficiency of up to 99 percent Also <br /> commonly used during soil vapor extraction/air sparging is one of the incineration processes (either <br /> catalytic oxidation or thermal oxidation) <br /> Catalytic oxidizers are used to destroy hydrocarbon vapors during soil vapor extraction, and operate most <br /> cost-efficiently at moderate vapor concentrations of 5- 25 percent of the lower explosive limit (LEL) (700 - <br /> 3,500 parts per million by volume (ppm(v))) Catalytic oxidizers are capable of destroying at least 95 <br /> percent of extracted hydrocarbon vapors within their optimum concentration operating range At <br /> concentrations higher than the maximum capacity of the equipment, dilution is required At concentrations <br /> of less than 5 percent LEL, auxiliary electricity is required <br /> Thermal oxidizers are used to destroy hydrocarbon vapors during soil vapor extraction, and operate most <br /> cost-efficiently at concentrations ranging from 25-60 percent LEL (3,500- 8,400 ppm(v)) Thermal <br /> ' oxidizers have a destruction efficiency of at least 95 percent At influent concentrations of more than 60 <br /> percent LEL, dilution is required At concentrations of less than 60 percent LEL, auxiliary fuel (natural gas) <br /> is required In varying amounts (more is required as concentrations decrease) Both catalytic and thermal <br /> oxidizers require electricity to operate, and thermal oxidizers require natural gas for combustion <br /> Although MTBE is not currently regulated by local air boards, it is anticipated that It will be sometime prior <br /> to the end of the cleanup period Therefore, the offgas treatment system will be designed to destroy <br /> MTBE vapors in addition to traditional petroleum constituents <br /> As an augmentation to groundwater extraction, this remediation method could be implemented upgradient <br /> of the extraction point, potentially reducing dissolved hydrocarbon concentrations prior to removal by the <br /> 1 <br />