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vo 470 Diesel Fuel Oil No 2-D 10
<br /> Section 6. Health Hazard Data
<br /> „ e
<br /> Carcinogenicity Although the IARC has not assigned an overall evaluation to diesel fuels as a group it has evaluated occupational exposures in
<br /> petroleum refining as an IARC probable human carcinogen(Group 2A) It has evaluated distillate(light)diesel oils as not classifiable as human
<br /> carcinogens(Group 3)
<br /> Summary of Risks Although diesel fuel s toxicologic effects should resemble kerosine s,they are somewhat more pronounced due to additives
<br /> such as sulfunzed esters Excessive inhalation of aerosol or mist can cause respiratory tract untation headache,dizziness, nausea,vomiting, and
<br /> loss of coordination,depending on couceatration and exposure time When removed from exposure'area, affected persons usually recover
<br /> completely If vormting occurs after ingestion and if oil is aspirated mto the Iungs,hemorrhaging and pulmonary edema,progressing to renal it
<br /> volrement and chemical pneumonitis, may result.A comparative ratio of oral to aspirated lethal doses may be 1 pt vs S ml Aspiration may also
<br /> result in transient CNS depression or excitemenL Secondary effects may include hypoxia(insufficient oxygen in body cells), infection,pneumato-
<br /> cele formation,and chronic lung dysfunction Inhalation may result in euphona,cardiac dysrhythmias,respiratory arrest, and CNS toxicity
<br /> Prolonged or repeated skin contact may unlace hair follicles and block sebaceous glands,producing a rash of acne pimples and spots,usually on
<br /> arms and legs e
<br /> Medical Conditions Aggravated by Long-Term Exposure None reported
<br /> Target Organs Central nervous system,skin, and mucous membranes
<br /> Primary Entry Rbutes Inhalation, ingestion _ - `
<br /> Acute Effects Systemic effects from ingestion include gastrointestinal irritation,vomiting,diarrhea,and it]severe cases central nervous system
<br /> depression,progressing to coma or death Inhalation of aerosols or mists may result in increased rate of respiration, tachycardia(excessively rapid
<br /> heart beat), and cyanosis(dark purplish discoloration of the skin and mucous membranes caused by deficient blood oxygenation)
<br /> Chronic Effects Repeated contact with the skin causes dermatitis
<br /> FIRST AID
<br /> Eyes Gently lift the eyelids and flush immediately and continuously with flooding am--unts of water until transported to an emergency medical ,
<br /> facility Consult a physician immediately t
<br /> Skin Quick f remove contaminated clothing Rinse with flooding amounts of water for at least 15 min If large areas of the body have been
<br /> exposed or ifirritation persists, get medical Help immediately Wash affected area with soap and water
<br /> Inhalation Remove exposed person Eo fresh air and support breathing as needed
<br /> Ingestion Never give anything by mouth to an unconscious or convulsing person If ingested,do not induce vomiting due to aspiration hazard
<br /> Contact a ph)'sicran immediately Position to avoid aspiration
<br /> %fter first aid,get ap roprlate !n-plant,paramedic,or community medical support
<br /> Note to Physicians �astric lavage is contraindicated due to aspiration hazard Preferred antidotes are charcoal and hulk In cases of sc%cre
<br /> aspiration pneumonitis,consider monitoring atlenal blood gases to ensure adequate ventilation Observe the patient for 6 hr If vital signs become
<br /> abnormal or symptoms develop, obtain aches[x-ray
<br /> Section 7. Spill, Leak, and Disposal Procedures
<br /> Spill/Leal. Notify safety personnel,evacuate area for large spills,remove all heat and ignition sources,and provide maximum explosion-proof
<br /> rcntilation Cleanup personnel should protect against vapor inhalation and liquid contact Clean up spills promptly to reduce fire or vapor hazards
<br /> Use a noncombustible absorbent material to pick-up small spills or residues For large spills,dike far ahead to contain Pick up liquid for reclama- -
<br /> tion or di eposal Do not release to sewers or waterways due to health and fire and/or explosion hazard Follow applicable OSHA regulations(29
<br /> CFR 1910 120) Diesel fuel oil No 2-D spills may be environmental hazards Report large spills w
<br /> Disposal Contact your supplier or a licensed contractor for detailed recommendations Follow applicable Federal,state, and local regulations
<br /> RPA Designations
<br /> µ
<br /> RCRA Hazardous Waste(40 CFR 261 21) Ignitable waste
<br /> CERCLA Hazardous Substance (40 CFR 302 4) Not listed
<br /> SARA Extremely Hazardous Substance(40 CFR 355) Not listed
<br /> vADA I —T:i 1-11111—L(4v C!J�J72.Vj) 1VUL iilLLd -- w
<br /> OSHA Designations — a
<br /> Air Contaminant(29 CFR 1910 1000,Subpart Z) Not listed
<br /> Section 8 Special-Protection Data - --
<br /> Goggles Wear protective eyeglasses or chemical safety gaggles,per OSHA eye-and face-protection regulations(29 CFR 1910 133)
<br /> Respirator Seek professional advice pnor to respirator selection and use Follow OSHA respirator regulations(29 CFR 1910 134) and,if neces-
<br /> sary,use a NIOSH-approved respirator with a mist filter and organic vapor cartridge For emergency or nonroutine operations(cleaning spills,
<br /> reactor vessels,or storage tanks), wear an SCBA Warnings Air-purifying respirators do not protect workers in oxygen deficient atmospheres
<br /> Other.Wear impervious gloves, boots, aprons,and gauntlets to prevent skin contact.
<br /> Ventilation Provide general and local explosion-proof ventilation systems to maintain airborne concentrations that promote worker safety and '
<br /> productivity Local exhaust ventilation is pmferred since it prevents contaminant dispersion into the work area by contrmlluig it at its source 000
<br /> Safety Stations Make available in the work area emergency eyewash stations,safety/quick-drench showers,and washing facilities
<br /> Contaminated Equipment Never wear contact lenses in the work area soft lenses may absorb, and all lenses concentrate,untantt Remove this
<br /> material from your shoes and equipment.Launder contaminated clothing before wearing
<br /> Comments Never cat,drink,or smoke in work areas Practice good personal hygiene after using this material,especially before eating,drinking, 1?
<br /> Smoking, using the toilet,or applying cosmetics
<br /> Section 9. Special Precautions and Comments
<br /> -Storage Requirements Use and storage conditions should be suitable for a OSHA Class II combustible liquid Store in closed containers in a
<br /> well-ventilated area away from heat and ignition sources and strong oxidizing agents Protect containers from physical damage To prevent static ,
<br /> sparks,electricallyand and bond all containers and equipment used in shipping,receiving,or transferring operations Use nonsparking tools
<br /> and explosion-proof ciccincal equipment No smoking in storage or use areas
<br /> Engineering Controls Avoid vapor or mist inhalation and prolonged skin contact.Wear protective rubber gloves and chemical safety glasses
<br /> where contact with liquid or high mist concentration may occur Additional suitable protective clothing may be required depending on working
<br /> conditions Institute a respiratory protection program that includes regular training,maintenance,inspection, and evaluation Practice,good,
<br /> personal hygiene and housekeepingprocedures Do not wear oil contaminated clothing At least weekly laundering of work clothes is recom-
<br /> mended Do not put oily rags in pockets Wheu working with this matenal, wear gloves or use bamcr cream
<br /> Transportation Data (49 CFR I72 101)
<br /> DOT Shipping Name Fuel oil
<br /> DOT Hazard Class Combustible liquid
<br /> ID No NA1993
<br /> DOT Label None
<br /> DOT Packaging Exceptions 173 118a
<br /> DOT Packaging Requirements None
<br /> t WSDSCol/ecdon References 1 6 7 12 73 84 101 103 126 127 132 133 136 143 146
<br /> Prepared b) M]Allison BS Industrial 11}glcne Rc%lcµ D1 Wilson CIH Nledlcal ReNfc" AC Darlington MD,Edited b} 1R Stuart MS 97 '
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