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1 <br /> mixtures is indirectly evaluated In fact, the conservative approach for quantifying risks <br /> associated with hydrocarbon mixtures makes use of indicator and/or surrogates (such as BTEX) <br /> for TPH-g and TPH-d (MDEP 1994), hence, results of this RBCA analysis may be used to <br /> ' formulate conclusions with respect to chemical constituents and hydrocarbon mixtures <br /> Selection of COPC source concentrations involved a detailed review of historical soil and <br /> ' groundwater quality data Based on removal via SVE operation of an estimated 1,551 pounds of <br /> hydrocarbons (EA 1998) from soils, the results of confirmation soil samples, and the potential <br /> ' for natural reduction of hydrocarbon levels detected historically (i e , 1991 and 1992) in tank <br /> basin product line samples, historical COPC levels in pre-remediation tank basin samples are not <br /> considered representative of the current or future magnitude of hydrocarbons present in <br /> ' unsaturated soils at the site Accordingly, soil COPCs and source concentrations correspond to <br /> maximum concentrations of chemicals detected in confirmation samples (post-remediation) from <br /> unsaturated soils beneath the former tank basin area Post-remediation soil samples from <br /> ' beneath the water table were not used to represent soil source concentrations, as the detected <br /> chemicals will not be subject to volatilization from beneath the water table Moreover, <br /> volatilization of chemicals from the saturated zone is already accounted for in evaluation of <br /> volatilization from groundwater <br /> Representation of groundwater COPC concentrations for onsite exposure pathways involved use <br /> ' of site maximum levels detected in all onsite wells over the past two years (see Table 1 of <br /> Appendix H) For offsite residential exposure to groundwater at the apartment building located <br /> 100 feet southeast of the site, COPC source concentrations corresponded to the maximum levels <br /> detected over the past two years in offsite downgradient well MW7 (see Table 1 of Appendix H) <br /> Use of maximum levels over the past two years as representative of current and future <br /> concentrations is considered conservative, given the absence of a continuous source and sporadic <br /> ' detection of hydrocarbons in groundwater (ETIC 2000) <br /> For evaluation of risks associated with direct exposure to groundwater at the <br /> ' agneultural/imgation wells located 14 miles south-southeast of the site, site maximum <br /> groundwater concentrations over the past two years were used to estimate potential exposure <br /> point concentrations at the wells This calculation assumed that the wells are perforated in the <br /> ' shallow water-bearing formation and that transport in groundwater is governed by advective and <br /> dispersive transport as depicted by the highly conservative Domenico solute transport model <br /> (ASTM 1995 and 1998, USEPA 1995, and Domenico 1987) Biodegradation and other mass- <br /> loss mechanisms were conservatively ignored along the path of chemical transport from the site <br /> to the wells Hydraulic parameters used in the Domenico model correspond to conservative <br /> ASTM (1995 and 1998) default values (see Appendix H), while plume dimensions correspond to <br /> highly conservative estimates based on the extent of hydrocarbon detection across the site <br /> Selected target nsk/hazard levels represent the most conservative values outlined by USEPA <br /> (1989, 1991), ASTM (1995 and 1998), and DTSC (1999) risk assessment guidelines Use of a <br /> target risk level of 1 x 10-6 is particularly conservative with respect to standard risk assessment <br /> practice for evaluation of exposure under commercial/industrial land use <br /> F ip,gects1701371Mmtei\%VplClosw e l IM0137mert doc 16 <br />