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1 Material Safety Data Sheet To& P 317 <br /> UENE <br /> Genlum Publishing Corporation (Revision D) <br /> 1145 Catalyn Street <br /> Schenectady,NY 12303-1836 USA Issued• August 1979 <br /> (538) 377-8855 cetaum Pusus"No cora I.Revised A nl 1986 <br /> SECTIONL MATERIAL IDENTIFICATION 20 <br /> MATERIAL hjAM TOLUENE HMI$ <br /> R 2 3 <br /> OTHER DESIGNATIONS Methyl Benzene,Methyl Benzol,Phenytmethane,Toluol. F3 2 0 <br /> C7Hg,CAS#0108-88-3 R. 0 <br /> MANUFACTURER/SUPPLIER Available from many suppliers,including *See SeCL 8 R1 <br /> Allied Corp,PO Box 2064R,Morristown,N) 07960,Telephone (201)455-4400 I 3 <br /> Ashland Chemical Co,Industrial Chemicals&Solvents Div,PO Box 2219, S 2 <br /> Columbus,OH,Telephone (614)889-3844 K4 <br /> SECTION 2. INGREDIENTS AND HAZARDS % HAZARD DATA <br /> Toluene ca 100 8-hr TLV 100 ppm,or <br /> CI-13 375 mg/m3- (Skin)" <br /> ,� Mai, lnhalat�on,TCLa <br /> �"�� 1 100 ppm..Psychotropic***- <br /> • Current(1985-86) ACGIH TLV The OSHA PEL is 200 ppm with an Rat,�.LD50 5000 mg&8 <br /> acceptable ceiling concentration of 300 ppm and an acceptable Rat,Inhalation,LCLo <br /> maximum peak of 500 pprivl0 minutes 4000 ppmt4 hrs <br /> '* Skin designation indicates that toluene can be absorbed through intact Rabbit,Skin,LD50 14 gmlkg <br /> skin and contribute to overall exposure -------------------- <br /> T kk4 Affects the mind Human,Eye 300 ppm <br /> SECTION 3 PHYSICAL DATA <br /> Boiling Point 231 F 01I'C) Evaporation Rate(BuAc= 1) 224 <br /> Vapor Pressure C 20'C, mm Hg 22 Specific Gravity(H20= 1) 0 866 <br /> Water Solubility C 20'C,wt % 0 05 Melting Point -139'F(-95'C) <br /> Vapor Density(Air= 1) 3 14 Percent Volatile by Volume ca 100 <br /> Molecular Weight 9215 <br /> Clear colorless liquid with a characteristic aromatic odor The odor is detectable to most individuals in <br /> the range of 10 to 15 ppm Because olfactory fatigue occurs rapidly upon exposure to toluene,odor is not a good warning <br /> propert} <br /> SECTION 4. FIRE AND EXPLOSION DATA LOWER UPPER <br /> Flash Paint and MethodAutoignition Temp Flammability Ltmtts In Air <br /> 40-F(4'C) CC -4896'F 480' %.b%.by Volume 127 71 <br /> EXTINGUI5HING MEDIA Carbon dioxide,dry chemical,alcohol foam Do not use a solid stream of water because the stream <br /> will scatter and spread the fire Use water spray W cool tankslcontamers that are exposed to fire and to disperse vapors <br /> * This OSHA class IB flammable liquid is a dangerous fire hazard It is a moderate fire <br /> hazard when exposed to oxidizers, heat, sparks,or open flame Vapors are heavier than air and may travel a considerable <br /> distance to an ignition source and flash back <br /> SPECIAL FIRE-FTGHTING PROCEDURES Fire fighters should wear self-contained breathing apparatus with full facepiece <br /> operated in a positive-pressure made when fighting fires involving toluene <br /> SECTION 5 REACTIVITY DATA <br /> CHEMICAL INCOMPA FIBIIITIES Toluene is stable inclosed containers at room temperature under normal storage and <br /> hand hog conditions It docs not undergo hazardous polymenzdtion This material is incompatible with strong oxidizing <br /> agents,dinitrogen tenwxide,silver perchlorate, tetranitromethane, and uranium hexafluonde Contact with these materials <br /> may cause fire or explosion Nitric acid and toluene,especially in the presence of sulfuric acid,will produce nitrated <br /> compounds that are dangerously explosive <br /> CONDITIONS TO AVOM Avoid exposure to sparks,open flame,hot surfaces,and all sources of heat and igniuon Toluene <br /> will attack some forms of plastics,ribber, and coatings Thermal decomposition or burning produces carbon dioxide and/or <br /> carbon monoxide <br /> Cavr,iRln O 1986 bemo wnit.h,ru Cap ua <br /> AnY caav Cw us a rep odvctm.�a.,Um putdnh&s permmim s prahm,ud <br />