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. NO <br /> SECTION VI HEALTH HAZARD INFORMATION TLV 5 ppm Ceiling Level (as HCl) <br /> rquantityg <br /> usHCl and its vapors are strong i ritants of the eyes, mucous mem ranee, and skin <br /> erity of eye injury from splashes from irritation to sepvere burns depepnds 9n <br /> irritates therupper resWatory tractsanc cant resultsinecou hin vaburn9nisof throat, choking sensation and, if inhaled deeply, pulmonary edema, Pgolonged or <br /> repeated low level exposure may cause teeth erosion. Skin exposure can cause burns; <br /> repeated or prolonged exposure to dilute soln may cause dermatitis. Ingestion can <br /> cause severe burns and possible laryngeal spasm. FIRST AID, <br /> E.Y�e__Co�ntac�t Contact physician+ Immediately flush with running wale—er_Fo 15 min. <br /> nl cluding under eyelids ' <br /> Skin Contact Flush affected area well with water. Remove grossly contaminated <br /> c of ng under safety shower. Get medical help if large skin area contacted or <br /> if irritation persists. <br /> Inhalation. Remove to fresh air. Restore and/or support breathing as needed. Use 0 <br /> t . <br /> ttonfiftni, difficult bh -3. medical <br /> Keep <br /> warm <br /> and ngevictim is conscious, give 2glassesof water, thenmilk ofmagnesia or <br /> l m er. Contact physician' Do not _induce vomiting! <br /> SECTION VII SPILL, LEAK AND DISPOSAL PROCEDURES <br /> eport large spills to safetyy personnel. Evacuation may be needed keep upwind Remove <br /> sources of ignition if H ma hazard. Provide optimum ventilation Those involved <br /> in clean-up of large spi$ls must use full protective clothing, boots, and self-contained <br /> breathinapparatus <br /> mall spills <br /> s and residues can be covered with excess of a mixture of soda ash and slaked <br /> line to neutralize, and the slurry pici.ed up for landfill burial or flushed with much <br /> water. <br /> o-atain large spills. Collect or flush with water to holding area for neutralization. <br /> Do not flush directly to sewer or surface Waters <br /> DISPOSAL Dispose of acid via licensed contractor or neutralize with limestone, soda <br /> s slaked lime Flushing to sewer depends on allowable neutral salt concentrations <br /> acidin ffluent water. F 1 v Federal State and Loca u n JSnsS6$6rlsrj4�f Cse17 <br /> to neutlraize a� mine waste. <br /> . SECTION VIII SPECIAL PROTECTION INFORMATION <br /> rovide adequate exhaust ventilation to aeet TLV requirements Face velocity of hoods <br /> should exceed 100 lfin. Lse approved resF,zrator or self-contained breathing apparatus <br /> for emergency or non-routine conditiors . ith full facepiece above 50 ppm <br /> Those handling hydrochloric acid should use protective clothing and equipment to prevent <br /> body contact with the liquid Use rubber gloves or gauntlets, apron, boots, long <br /> sleeved shirt, body suit, etc. Use che=.cal safety goggles and/or face shield for eye <br /> protection against splashing of acid <br /> An e)ewasn station, washing facilities, a-: safety shower must be readily availaole to <br /> areas of use and handling. <br /> SECTION IX SPECIAL PRECAUTIONS AND COMMENTS <br /> Store closed containers out of direct su—icht, in a clean, cool, open or well-,,entilated <br /> area auay from oxidizing atents, away from alkaline material and sources of heat Area <br /> should have acid resistant oor and epiroved drainage. Protect containers from physical <br /> damage. Use nonsparking tools in areas around tanks and pipes where hydrogen might be <br /> generated. <br /> Use with good ventilation Avoid inhalaticr of HC1 vapors Odor of HC1 gives adequate <br /> warning for a prompt voluntary withdra..al from excessive exposure Do not get in eyes <br /> or on skin or clothing. Wash thorough!% after handling <br /> Provide emergency neutralization materials and equipment near storage and use areas. <br /> DOT Classification CORROSIVE MATERIAL I.D. No UN1789 Label- CORROSIVE <br /> I'10 Class 8 <br /> DATA SOURCE(S) CODE 1-12,14-16,27,31,34,37,38,47-49 <br /> Jaywr+ as a or awao+ry a+rern,rah hwvn piens+*+ aroew r. -+*+ww APPROVALS MIS,CRD <br /> prPapr t SUM+Bk, Taw~, aMVWh Ca#has Owl 4kM n rm^K. LM <br /> wcz+"v w 6�Pw).w CnSXXKO M V,614n Mrkft roov INDUST HYGIENE,SAFETY <br /> a.�rw no r"ro�nfmy a+to..*=,racy a wuw.Y a,,Kn+,re..we.,b apcw-. V w <br /> C dr f^M WC?wholes a b c01%680, a+Of n.. <br /> MEDICAL REVIEW 15 June 1964 <br /> GENI UM PUBLISHING <br />