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Ground-Water Sampling <br /> k- Senior Specialist Steve Sasson of the San Joaquin County Environmental Health Division was <br /> again on-site to witness monitoring activities. Prior to normal well-sampling procedures, <br /> ground-water sampling equipment was steam-cleaned and/or washed in Liquinox® prior to <br /> sampling and between sampling each well. Water-condition parameters of temperature, <br /> electrical conductivity, and pH were measured and logged during well-purging prior to sampling <br /> the wells. Purging was continued until at least three well-volumes of water were removed from <br /> G`1 <br /> each well, and water condition parameters had stabilized. The Well Sampling and Monitoring <br /> Logs are included as Appendix A. <br /> >; Each ground-water sample was collected within a clean, disposable, polyethylene bailer lowered <br /> to just below the water surface. Each ground-water sample was brought to the surface and <br /> immediately transferred to two-to-six, 40-m1 capacity, glass, Volatile Organic Analysis (VOA) <br /> vials and fitted with Teflon''"-lined screw caps. Care was taken to ensure that no air space <br /> existed in the vials by inverting, tapping, and checking for bubbles. Each container was <br /> properly labeled in the field and refrigerated for transport to Sherwood Labs in Hilmar for TPH- <br /> ? j g by EPA Method 5030/8015-mad and BTEX analytes by EPA Method 602. <br /> Sherwood forwarded a portion of the sample collected from MW-6 to Associated Laboratories <br /> in Orange for newly-required analysis for methyl-t-butyl ether (MTBE), a constituent listed in <br /> EPA Method 8260 - Volatile Organics by Capillary Column. An analysis for MTBE is required <br /> only once should nondetectable results be reported. <br /> TEPH-d analysis by EPA Method 3510/8015-mod was again not required for this second quarter- <br /> 1996 activity because diesel analytes have not been detected in past sampling activities. <br /> Appropriate chain-of-custody procedures were adhered to at all times during sample procurement <br /> and handling. The samples were extracted and analyzed within the lifespan limits set forth by <br /> EPA guidelines for the specified analyses. <br /> Analytical Results <br /> Ground-water samples collected from the five wells were received at Sherwood Labs on March <br /> 18, 1996. The analytical results revealed continuing nondetectable TPH-g and BTEX in samples <br /> j collected from wells MW-4, MW-5, and MW-7. Also, no detectable gasoline analytes were <br /> ' detected in the sample collected from MW-8. <br /> } The results of the gasoline analyses of the sample collected from MW-6 indicate that the ground <br /> water underlying that vicinity remains impacted. TPH-g and benzene analytes have increased <br /> .. since January 16. It is possible that tidal influence may be at least partly responsible. Only <br /> benzene exceeds the Maximum Contaminant Levels (MCLS) set by the California Department <br /> ` of Health Services. TPH-g and benzene had declined approximately 33% between October 18, <br /> 1995 and January 16, 1996. Concentrations of toluene, ethylbenzene, and total xylenes have <br /> W.W.Irwin, Inc. <br /> Project No. 33016.06 <br /> April 1996 10 <br /> i <br />