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WASTE DISCHARGE REQUIREMENTS ORDER NO.R5-2002-0071 -7- <br /> CALIFORNIA NATURAL PRODUCTS <br /> WASTEWATER TREATMENT FACILITY <br /> SAN JOAQUIN COUNTY <br /> 42. The depth to groundwater is approximately 10 to 15 feet bgs and the groundwater gradient is <br /> reportedly to the northwest and west, although locally, groundwater depth and flow may be <br /> influenced by local pumping and irrigation patterns. <br /> 43. The average analytical results for groundwater samples collected from May through September 2001 <br /> from Wells W-1 through W-4, and L-1 through L-3 are presented below. Earlier analytical data is not <br /> presented because it is considered to be low quality and therefore unreliable. <br /> 17.6 Acre Area Proposed 16.0 Acre Area <br /> Analytes Units Average (W-1 throu W-4) Average (L-1 through L-3) <br /> pH Std. 7.26 7.83 <br /> TDS mg/1 1,492 512 <br /> NO3 as N mg/1 39.6 20.8 <br /> TKN mg/1 ND (0.50) ND (0.50) <br /> TDS denotes Total Dissolved Solids. NO3 as N denotes Nitrate as Nitrogen. TKN denotes Total Kjeldahl Nitrogen. <br /> 44. As indicated in the table above, the average TDS concentration in the groundwater below the <br /> current land application areas is almost three times higher than that of the groundwater below the <br /> area that has not yet been used for land application, and the average nitrate (as nitrogen) <br /> concentration in the groundwater below the current land application areas is almost twice as high <br /> as that of the groundwater below the area that has not yet been used for land application. This <br /> data, coupled with the reported groundwater gradient to the northwest, indicates that groundwater <br /> below the 17.6 acre land application area and 9.2 acre landscaped area may be impacted by the <br /> discharge of wastewater from the facility. It is noted that none of the wells in the 17.6 acre land <br /> application area are located upgradient of wastewater application activities, therefore, the <br /> Discharger must install additional background wells. A similar situation will exist at the 16.0 acre <br /> land application area once wastewater application begins. <br /> 45. These WDRs require monitoring of shallow groundwater conditions, including background water <br /> quality and direction of groundwater movement throughout the year. <br /> 46. The Discharger has substituted certain chemicals in the processing facility with more <br /> environmentally acceptable alternatives (i.e. potassium hydroxide for sodium hydroxide, and nitric <br /> or phosphoric acid for pH neutralization) resulting in wastewater with more plant nutrients. This <br /> approach should result in lower TDS percolate concentrations when applied to cropped land <br /> application areas. In addition, the Discharger began growing crops on the 17.6 acre land <br /> application area in the year 2001; both actions should lead to a reduction in TDS and nitrate <br /> concentrations beneath the 17.6 acre land application area. If reductions are not observed, the <br /> Discharger will have to reduce the groundwater impacts through other alternatives. <br /> SITE SPECIFIC CONDITIONS <br /> 47. Local land use consists of industrial,residential, and agricultural operations. The topography of <br /> the surrounding area is level. <br />