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with a special septum "valve" and tubing bib, to the sample port . <br /> The sample port is on the vaccum side of the pump and therefore a <br /> vacuum greater than the well vacuum must be exerted on the <br /> outside of the tedlar bag to " fill" the bag with the vapor <br /> sample A special vacuum box, in which the tedlar bag is sealed <br /> inside, is used to exert a high vacuum to the exterior of the <br /> bag, thereby pulling a sample into the bag Once the tedlar bag <br /> is filled, its valve is closed and locked and the appropriate <br /> label is placed on the bag <br /> The label shows the date, time, sample ID# and analyses to be run <br /> and the sampler' s initials The tedlar bag samples are then <br /> placed within a cooler, and are hand delivered to WEGE' s <br /> laboratory that same day <br /> The vapor sample is then in3ected into an FID (Flame Ionizing <br /> Detector) chromatograph and the resulting chromatogram compared <br /> to standard chromatograms of known TFH (Total Fuel Hydrocarbons, <br /> gasoline) and BTEX (benzene, toluene, ethylbenzene, and xylenes) <br /> concentrations A dual chromatograph comparison is also run <br /> (Photovac 10550) to evaluate BTEX, TCE, PCE, and DCE <br /> Carbon dioxide (CO2) concentration is measured in the tedlar bag <br /> samples by connecting a Drager tube to the inlet of the tedlar <br /> bag that measures only CO2 reaction in percent any using a Drager <br /> pump to move the sample through the tube A direct reading in <br /> percent is then obtained and recorded on the chrmoatogram <br /> produced from the GC-FID analysis <br /> ON SITE ANALYSIS <br /> During the two hour tests, a photoionizing detector (HNu PTD <br /> w/10 2 ev bulb) and/or GasTech LEL/02 meter are used to perform <br /> constant exhaust monitoring, see Field Notes - Appendix A The <br /> LEL was used to insure that less than two pounds of hydrocarbons <br /> would be emitted during the test A common used LEL for gasoline <br /> is 1 . 40-. = 14, 000 ppmv * mg/L/250 ppmv * 6 21X10-5 * flow rate <br /> (cfm) * 120 minutes = 1 04 lb at 5% LEL and 2 08 lbs at 10% LEL <br /> The extraction well vacuum and flow is measured with a mercury <br /> manometer and the surrounding wells were gauged with a water <br /> manometer <br /> FLOW RATES <br /> Flow rates are measured at the site by use of a orifice plate A <br /> one inch orifice-sampling manifold is placed directly on the <br /> casing of the monitor well , carefully avoiding any vacuum leaks <br /> An orifice plate restricts the flow of air across it . This <br /> restriction causes a pressure drop across the orifice By <br /> measuring the resulting pressure change across the orifice it is <br /> possible to calculate the air flow rate The flow rate is <br /> calculated by the pressure drop (millimeters (mm) mercury or <br /> water) across a square edge orifice plate. <br /> PAGE 3 <br />