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OVER-EXCAVATION AND DOCUMENTATION SAMPLING <br /> Upon removal and sampling of the existing double contained fiberglass piping system, it was <br /> discovered that older abandoned steel piping still existed beneath the dispenser areas The old <br /> piping system was inspected and removed on February 25, 2000 Letitia Bi eggs, Senior Registeied <br /> Environmental Health Specialist, Public Health Services, San Joaquin County (PHS-SJC) noted <br /> obvious soil contamination beneath the southernmost and south central dispenses areas and directed <br /> confirmation sampling for documentation (samples SBI, SB2, SB3, SB4 SB5 and S135), see Table <br /> 1, Figure 6 Appendix B —Laboiatory Reports and Appendix C —Field Notes <br /> Western Geo-Engineers, updated the Risk Base Corrective Action Tiet 2 (RBCA Tier 2) modeling <br /> based on the above obtained soil samples, Appendix D The main concern was leachability to <br /> gioundwatei from soil contaminants (gasoline range hydrocarbons) left in place The RBCA Tiei 2 <br /> indicated that the following concentrations in soils could remain, Benzene at 0 011 mc,/Kg, Toluene <br /> at 6 6 ing/Kg, Ethyl Benzene @ 2 4 mg/Kg and MTBE at 0 22 mg/Kg Xylenes risk based target <br /> concentration is greater than constituent residual saturation value <br /> Ovei-excavationwas directed by Mr Michael Infurna of PHS-SJC, pre-approval had been obtained <br /> from the State Water Resources Control Board, see Appendix A Over-excavation occurred in <br /> three areas the southernmost dispenser area (PIT 1) at sample point PL-6 (PIT 2) and the southern <br /> middle dispenser area (PIT 3) <br /> FIELD SCREENING OF SOILS EXPOSED IN THE OVER-EXCAVATION AREAS <br /> ASSOCIATED WITH THE PRODUCT DISPENSING SYSTEM EXCAVATIONS <br /> Upon removal of the product dispensing piping the native soils were field screened using a photo- <br /> ionizing detector (PID) with a 10 2 ev bulb Once the PID showed no responses, approximately 20 <br /> grams of that soil was placed into a 40 cc VOA vial, capped and Heated on a hot plate to volatilize <br /> any petroleum hydrocarbons that still may exist in the soils A 0 5 cc sainple of the headspace of <br /> the soil san-ipte was then obtained and injected into a field gas chromatograph with a 10 2 ev PID <br /> The responding gas chromatogram was then compared to a standard chromatogram which <br /> contained 10 mg/I. degraded gasoline and 0 05 mg/L benzene Based on this field scieening a <br /> decision was made if further excavating was needed or confirmation samples were obtained This <br /> detector is sensitive to volatile organic compounds that have an electron potential of of less than <br /> 102 ev Gasoline vapors ate readily detected with this detector and it is the preferred field- <br /> screening instrument for soils at suspected gasoline-contannrnated sites <br /> PIT I <br /> Em,avating of the southernmost dispenser area commenced on March 1, 2000, based primarily on <br /> sample South Dispenser which contained 86 mg/Kg TPHg and 0 053 mg/Kg Benzene or 5 tine the <br /> amount that was predicted could be left in place and secondary on odor and visual staining An <br /> estitnatud 24 yards of gasoline contaminated soils (PIT 1) was removed and placed on plastic liner <br /> foi later removal and disposal In the process of excavating the gasoline-contaminated soils from <br /> Pit 1, the footing supporting the canopy was exposed, see Figure 7 Neil 0 Anderson (ROE 2245) <br /> R-603 over-ex 4-2000 <br />