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a <br /> Chemical Analytical Methods and Results <br /> Eight groundwater samples were analyzed using EPA Methods 503018015, 602 and 8260 for Total Petroleum <br /> Hydrocarbons as Gasoline (TPHG), Benzene, Toluene, Ethylbenzene and Xylene (BTEX) and fuel oxygenates <br /> Including Methyl-tert-butyl-ether (MTBE), Tert-Butyl Alcohol (TBA), Di-Isopropyl Ether (DIPE), Ethyl tert-butyl <br /> ether(ETBE), Tert-Amyl Methyl Ether TAME) The analytical results of the groundwater samples for this sampling <br /> event are attached and listed below in Table 1 (and Figures 2, 3 and 4) and historic data is presented to attached <br /> spreadsheet Table 2) - _ <br /> Table 1 Current Quarter Groundwater Chemical Data(December 23,2002) <br /> Sample TPHG Ben TO] Ethvl a] MTBE TBA D1PE ETBE TAME <br /> UO ugA u I u I u u l ugfl u <br /> UO u <br /> MW-I ND ND ND ND ND ND ND ND ND ND <br /> MW-2 1400 ND ND 23 88 ND ND ND ND ND <br /> MW-3 290000* 280 740 3200 16000 ND ND ND ND ND <br /> MW-4 ND ND ND ND ND ND ND ND ND ND <br /> MW-5 ND ND ND 16 44 ND ND ND ND ND <br /> MW-6 No data No data No data No data No data No data I No data I No data No data No data <br /> MW-7 ND ND 077 ND ND ND ND ND ND ND <br /> MW-8 ND ND ND 36 12 ND ND ND ND ND <br /> MW-9 190000# 940 310 $100 17000 ND ND ND ND ND <br /> Blank ND ND ND ND ND ND ND ND ND ND <br /> ND-None detected LIM-micrograms per liter Ben-Benzene Tot-Toluene X%I-Xvlene <br /> Fuel Ox -Fuel Oxvaenates by Method 82.60 from Dec 1997 forward Ethvl-Ethvibenzene <br /> 1 2 Dtchloroethane and Ethklene Di bromide ND in all wells these analvses discontinued to 2000 <br /> * 0 12 inches o1 degraded product present on water inwell at time of sampling <br /> #-0 03 inches of degraded product present on water in well at time of sampling <br /> No data—Not sampled due to car parked over well on Dec 23,2002 <br /> Discussion <br /> Groundwater flow direction is northerly at a flow gradient that is consistent with historically observed trends (see <br /> Figure 1) Groundwater levels have declined slightly In wells since the last quarter TPHG levels increased in <br /> wells MW-3 and MW-9, and declined in Well MW-2 Benzene concentrations declined in Well MW-3 and only <br /> increased slightly in MW-9 Floating product was present in MW-3 (apparent 0 12 feet) and in MW-9 (apparent <br /> 0 03 feet) MTBE and fuel oxygenates were not detected in any well <br /> Contaminant TPHG concentrations increased in MW-3 and MW-9 and declined slightly in MW-2 Wells MW-3 and <br /> MW-9 have historically shown elevated concentrations on the site and observed fluctuations have been interpreted as <br /> local contaminant desorption from sediment near the casing Separate phase product was observea in MW-3 and <br /> MW-9 dunng this sampling and the increase In TPHG is attributed to the presence of this degraded product in the <br /> wells and sample collection However the presence of product did not cause a large rise in BTEX volatile content <br /> (and Benzene decreased in Well MW-3) which in our opinion indicates a dissolved plume of degraded fuel depleted <br /> in dissolved volatile constituents (see Figures 2, 3 and 4) <br /> I <br /> Page 2 <br />