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STANDARD OPERATING PROCEDURE - <br /> QUARTERLY GROUNDWATER SAMPLING <br /> GeoStrategies field personnel adhere to the following procedures for the collection and handling of <br /> groundwater samples prior to analyses by the analytical laboratory. Prior to sample collection, the type <br /> of analyses to be performed is determined. Loss prevention of volatile compounds is controlled and <br /> sample preservationfor subsequent analyses is maintained. <br /> Prior to sampling, the presence or absence of free-phase hydrocarbons is determined using a MMC flexi- <br /> dip interface probe. Product thickness, if present, is measured to the nearest 0.01 foot and is recorded <br /> in the field notes. In addition, static water level measurements are collected with the interface probe and <br /> are also recorded in the field notes. <br /> After water levels are collected and prior to sampling, each well is purged a minimum of three well <br /> casing volumes of water using pre-clean pumps (stack, suction, Grundfos), or polyvinyl chloride bailers. <br /> Temperature, pH, and electrical conductivity are measured a minimum of three times during purging. <br /> Purging continues until these parameters stabilize. <br /> Groundwater samples are collected using disposable bailers. The water samples are transferred from the <br /> bailer into appropriate containers. Pre-preserved containers, supplied by analytical laboratories are used <br /> when possible. When pre-preserved containers are not available, the laboratory is instructed to preserve <br /> E= the sample as appropriate. Duplicate samples are collected for the laboratory to use in maintaining <br /> duality assurance/quality control standards. The samples are Iabeled to include job number, sample <br /> identification, collection date and time, analyses, preservative (if any), and the sample collector's initials. <br /> The water samples are placed in a cooler, maintained at 4 C for transport to the laboratory. Once <br /> collected in the field, all samples are maintained under chain-of-custody until delivery to the laboratory. <br /> The chain-of-custody includes the job number, type of preservation, if any, analyses requested, sample <br /> identification, date and time collected, and the sample collector's name. The chain-of-custody is signed <br /> and dated (including time of transfer) by each person who receives or surrenders the samples, beginning <br /> with the field personnel and ending with the laboratory personnel. <br /> A laboratory-supplied trip blank accompanies each sampling set. For sampling sets greater than 20 <br /> samples, 5% trip blanks are included. The trip blank is analyzed for some or all of the same compounds <br /> as the groundwater samples. <br /> SOn.QRS/Rev 2196 <br />