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CAP Addendum:Former FueQ Station, 7500 West Eleventh Street, Tracy, CQ Page 10 <br /> the processes of natural attenuation that are currently acting to dissipate the <br /> concentrations of analytes of concern in groundwater. These issues are discussed below. <br /> 2.3 Optimal Amount of Contaminant Mass to be Removed <br /> To assess the optimal mass of components of fuel hydrocarbons that should be removed <br /> from the subsurface by the proposed remediation technology, consideration must be <br /> given to processes of natural attenuation that are active in the soil and groundwater in the <br /> area affected by LNAPL. <br /> 2.3.1 Aerobic and Anaerobic Processes of Natural Attenuation <br /> SJC has completed an evaluation of natural attenuation processes active in the subsurface <br /> beneath the Navarra Site (The San Joaquin Company Inc 2006). That study showed that <br /> aerobic natural attenuation processes were clearly active in groundwater at the locations <br /> of all groundwater monitoring wells (see Figure 1 for locations) except in the area around <br /> Monitoring Wells MW-7 and MWFP-1. <br /> Figures 5 and 6 are plots of the distributions of the natural logarithms of concentrations <br /> of BTEX and dissolved oxygen and the natural logarithms of concentrations of BTEX: <br /> and reduction oxidation potential (Redox Potential), respectively, along <br /> Hydrostratigraphic Section C-C' (see Figure 1 for location and Figure 3 for <br /> hydrostratigraphy), which section passes through, or close to, both Monitoring Wells <br /> MW-7 and MWFP-1. <br /> As cited in Table 4, the Redox Potential of the groundwater in those two wells as <br /> measured in February 2005 was -246.7 mV and -142.4 mV, respectively. Negative <br /> values of Redox Potential are indicative of anaerobic conditions in the groundwater. As is <br /> also cited in Table 4, the chemical oxygen demand of the dissolved material in <br /> groundwater in Monitoring Wells MW-7 and MWFP-1 are both high at 22 mg/L and 50 <br /> mg/L, respectively. High chemical oxygen demand is indicative of an environment that is <br /> unlikely to support aerobic natural attenuation processes. <br /> As a general rule of thumb, 5.0% dissolved oxygen in groundwater affected by fuel <br /> hydrocarbons is considered the minimum required to support aerobic processes of natural <br /> attenuation. In February 2005, there was only 3.2% dissolved oxygen in the groundwater <br /> in Monitoring Well MW-7. That, taken together with the values other geochemical <br /> parameters measured during the natural attenuation study, reveals that, at that time, <br /> anaerobic conditions prevailed in groundwater in the area around that well. At that time, <br /> the concentration of total petroleum hydrocarbons in the groundwater at that well (i.e., <br /> approximately the sum of the concentrations of TPHd and TPHg) that are recorded in <br /> Table 2 was 33,000 p.g/L and the apparent thickness of LNAPL floating on the surface of <br /> the groundwater as recorded in Table 1 was 0.02 ft. <br /> Evidence that dominantly anaerobic conditions were prevailing in Monitoring Well <br /> MWFP-1 in February 2005 is less strong. Although, as was noted above, the Redox <br />