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Report: Groundwater-quality Monitoring—October 25, 2002: 7500 West Eleventh Street, Tracy, Cil. Page 12 <br /> aquitard that is present beneath the 7500 West Eleventh Street property at a depth of <br /> approximately 20 ft. See Figures 3 through 5 for h drostrati a b This was also the <br /> ' case when those wells were sampled on July 29, 2002. However, in the samples <br /> h } recovered from Monitoring Wells 3A, 3B and 12A on October 25, 2002, the laboratory <br /> reported the presence of a compound that was NOT a fuel hydrocarbon, but that included <br /> components with molecules having carbon-chain lengths within part of the same range <br /> that includes compounds that are components of diesel. The concentrations of those <br /> molecules in the samples ranged from 100 to 150 µg/L. Because the molecules detected <br /> are part of an unidentified compound that does not match the laboratory standard for any <br /> fuel hydrocarbon that was released into the subsurface at the 7500 West Eleventh Street <br /> site, the concentration of diesel detected in samples of groundwater recovered from <br /> Monitoring Well 3A, 3B and 12A on October 25, 2002 has been entered as ND (not <br /> detected) in Table 2, but the presence of the unidentified molecules has been noted in the <br /> footnotes to that table. <br /> j Examination of Table 1 shows that the pieziometric level in the near-surface aquifer <br /> monitored by Monitoring Wells MW-3 and MW-12 is slightly higher than the <br /> pieziometric heads in the aquifers monitored by MW-3A, MW-12A, and MW-3B. Thus, <br /> =_ there is a positive downward vertical gradient, although small, between the near surface <br /> aquifer and the deeper aquifers. However, when the stratigraphy and geochemistry of the <br /> site are examined (see Figures 2, 4, 5 and Table 2), it is clear that if the source of the <br /> J unidentified compound in Monitoring Wells MW-3A, MW-3B and MW-12A had <br /> reached the deeper aquifer by downward migration from the shallow aquifer that is <br /> affected by components of hydrocarbon fuel, when first detected on October 25, 2002, <br /> they should have contained MTBE or molecules in the range typical of gasoline, which <br /> compounds migrate through soil at a much faster rate than the longer-chain molecules <br /> _# that were observed in the samples. Therefore, it appears unlikely that the apparent <br /> contamination of the deeper aquifers seen in the October 25, 2002 samples could have a <br /> source in the affected near-surface aquifer beneath the site. <br /> SJC and STL have studied the analytical data obtained from each of the samples <br /> recovered on October 25, 2002. Based on the field procedures used and the order in <br /> which the samples were recovered, SJC can see no evidence that the compounds detected <br /> in Monitoring Wells 3A, 3B and 12A could have been introduced into the samples from <br /> contaminated equipment. <br /> " <br /> SJC then considered the possibility that the unidentified compounds in the samples were <br /> components of turbine oil used to lubricate pumps in agricultural or domestic wells <br /> 4 located in the neighborhood. Contamination of groundwater by oil drip-fed into turbine <br /> pumps in agricultural and domestic wells is a common source of groundwater <br /> contamination in the Tracy area. However, local inquiry found that turbine pumps were <br /> not currently in use in any of the close-by wells and, in so far as it is known, have not <br /> been used in those wells in the recent past. <br /> SJC also considered the possibility that the deeper aquifers had become contaminated by <br /> some unknown material being spilled on the surface and passing downward into the <br /> sic <br /> " .I <br />