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Evaluation of Natural Attenuation: 7500 West Eleventh Street, Tracy, CA. Page ii <br /> 7.1 Primary Evidence of Natural Attenuation.......................................................................... 24 <br /> 0 7.1.1 Attenuation of Analytes of Concern with Distance from the Source......................... 24 <br /> 7.1.2 Attenuation of Analytes of Concern with Time................................... .. . ... <br /> 7.1.2.1 Time Required for Complete Remediation of Contaminants in Source Area..... 27 <br /> 7.1.3 Mass Balance of BTEX in Groundwater.................................................................... 28 <br /> 7.2 Secondary Evidence for Natural Attenuation..................................................................... 32 <br /> ! 7.2.1 Evidence for Aerobic Biodegradation........................................................................ 33 <br /> 7.2.1.1 Dissolved Oxygen in Groundwater . 33 <br /> 7.2.1.2 Oxidation Reduction Potential............................................................................ 34 <br /> f.l <br /> 7.2.2 Evidence for Anaerobic Respiration........................................................................... 34 <br /> 7.2.2.1 Ferrous Iron in Groundwater................ ...................... ........... 35 <br /> 7.2.2.2 Total Dissolved Iron............................................................................................ 36 <br /> p._j 7.2.2.3 Manganese..............................•.................... ..... 36 <br /> ................................................... <br /> 7.2.2.4 Sulfate.................................................................................................................. 37 <br /> 7.2.2.5 Methane............................................................................................................... 37 <br /> i 7.2.2.6 Carbon Dioxide...................................... .... 37 <br /> . ....................................................... <br /> ! 7.2.2.7 Nitrates <br /> 7.2.3 Other Geochemical Indicators.................................................................................... 38 <br /> 7.3 Summary of Evidence of Active Bioremediation............................................................L. 39 <br /> 8.0 OPTIMAL MONITORING DATES AND FREQUENCY...............................................L-41 <br /> 8.1 Optimal Monitoring Dates.................................................................................................41 <br /> 8.2 Efficient Sampling Fre <br /> p g q uenc <br /> Y.................. .....43 <br /> i 8.2.1 ASTM Standard E 1943-98 Guidance.....................•. <br /> 8.2.2 US-EPA Guidance......................................................................................•...............43 <br /> 8.2.2.1 MAROS Input Data.......................... ........................................................44 <br /> 8.2.2.2 Plume Stability .... 44 <br /> 8.2.2.3 Well Redundancy Analysis............................................. <br /> 8.2.2.4 Optimal Sampling Frequency..............................................................................47 <br /> 8.2.2.5 Summary of MAROS Analysis...................... ........49 <br /> 9.0 CONCLUSIONS........................................................................................ ........ 50 <br /> .................... <br /> ' t <br /> 10.0 RECOMMENDATIONS ..... 52 <br /> 10.1 Technology for Groundwater Remediation....................................................................... 52 <br /> 10.2 Groundwater-quality Monitoring Program <br /> 10.2.1 June 2005 -March 2006 Quarterly Monitoring......................................................... 52 <br /> .......................... <br /> 10.2.2 March 2006 MAROS Analysis.................................................................................. 53 <br /> 10.2.3 Optimal Scope and Frequency of Long Term Monitoring . 53 <br /> 10.2.4 Suite of Analytes to be Monitored............................................................................. 53 <br /> 10.3 Monitoring of Potable Water Quality ............................................................................... 54 <br /> 11.0 REFERENCES.......................................................................... <br /> TABLES <br /> 'i <br /> Table 1: Depths to Groundwater <br /> Table 2.- Results of Analyses of Samples of Groundwater <br /> jTable 3: Thickness of Floating Product in Monitoring Well MW-7 <br /> _J <br /> Table 4: Results of Analyses of Samples from Potable Water Wells <br /> Table 5: Natural Attenuation Data <br /> Sic <br />