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Evaluation of Natural Attenuation: 7500 West eleventh Street, Tracy, CA. Page 3 <br /> number of wells sampled for the July 2003, October 2003 and January 2004 monitoring <br /> rounds (The San Joaquin Company 2004e, 2003c, 2003b) were reduced at the direction <br /> of the San Joaquin County Environmental Health Division (SJCEHD) to the sampling of <br /> 1: seven, ten and seven of the 15 groundwater-quality monitoring wells, respectively. <br /> The fourteenth monitoring round was conducted on April 21, 22 and 30, 2004, when <br /> f: groundwater samples were recovered from the 15 pre-existing wells and the seven new <br /> groundwater-quality monitoring wells installed in that month (The San Joaquin Company <br /> 2004d). The fifteenth and sixteenth monitoring rounds included all 22 groundwater- <br /> quality monitoring wells and were conducted on Jul 26-27 and October 27-28 2004 <br /> q Y g Y , <br /> respectively(The San Joaquin Company 2004b, c). <br /> This report documents the seventeenth quarterly monitoring round, which was conducted <br /> at the 7500 West Eleventh Street site over the period February 24-March 16, 2005. That <br /> round also included sampling of all 22 groundwater-quality monitoring wells extant at the <br /> =:1 Navarra Site at that time and was conducted in conjunction with an evaluation of natural <br /> attenuation of chemicals of concern in groundwater at the site. <br /> 1.3.3 Monitoring-of LNAPL <br /> This report also includes records from a program of monitoring the thickness of light <br /> non-aqueous phase liquid (LNAPL), present as floating product, in an array of five <br /> floating product monitoring wells and three selected groundwater-quality monitoring <br /> wells. <br /> When groundwater was first recovered from groundwater-quality monitoring well MW-7 <br /> on May 11, 2000, the sample contained moderate concentrations of Total Petroleum <br /> Hydrocarbons quantified as diesel (TPHd) and Total Petroleum Hydrocarbons quantified <br /> as gasoline (TPHg), with commensurate concentrations of benzene, toluene, ethyl <br /> benzene and total xylene isomers (the BTEX compounds) and 22 p.g/L of methyl-tertiary <br /> butyl ether (MTBE), a fuel oxygenate. Thereafter, the concentration of components of <br /> fuel hydrocarbons followed an increasing trend until the analytes of concern exceeded <br /> their maximum solubility in water(see Table 2). However, as early as the sampling round <br /> 1 performed on November 28, 2000, no MTBE was detected in the samples recovered from <br /> Monitoring Well MW-7. It is believed that this does not indicate that, by that time, the <br /> groundwater in the vicinity of that well was free of MTBE. Rather, it indicates that the <br /> high concentrations of other components of fuel hydrocarbons were such as to raise the <br /> method detection limit (MDL) of the MTBE analysis to a level greater than the <br /> concentration of that analyte actually present in that groundwater sample. <br /> By April 11, 2002, it was clear that floating product was present in the surface of the <br /> groundwater in Monitoring Well MW-7. It continued to be present at various apparent <br /> thicknesses up to 0.58 ft. until an LNAPL-purging program in that well was initiated on <br /> f November 8, 2003. As part of the further extension of the site characterization program in <br /> April 2004, five floating product monitoring wells were installed at the locations shown <br /> on Figure 2 to investigate the down-gradient extent to which LNAPL may have migrated <br /> sic <br /> ;� i <br />