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b— Report:Groundwater-quality Monitoring—March 24-31,2006, 7500 West Eleventh Street, Tracy, CA Page 12 <br /> STL is certified to perform the specified analyses by the California Department of Health <br /> Services (DHS). <br /> +-- The results of the analyses of samples of groundwater are presented in Table 2, which <br /> also includes the results of analyses of groundwater samples recovered from all previous <br /> sampling rounds. Copies of the laboratory Certificates of Analysis generated from the <br /> L- March 2006 monitoring round are included in Appendix C of this report. <br /> 2.5 Groundwater Quality in the Near-Surface Unconfined Aquifer <br /> The results of analyses of samples of groundwater recovered in March 2006 are evaluated <br /> below. <br /> 2.5.1 Anal es of Concern in Groundwater Along Principal Plume Axis <br /> Monitoring Wells MW-3, MW-13, MW-7, MWFP-4 and MW-18, are, as is shown on <br /> Figure 3, arrayed along the approximate long axis of the primary plume of affected <br /> groundwater. As can be seen by inspection of Table 2, compared to the concentrations of <br /> analytes of concern that were found in the groundwater samples recovered from those <br /> wells in December 2005, the concentrations in the samples recovered in March 2006 <br /> were generally lower than those measured in samples recovered from the same wells. For <br /> example, the concentration of benzene in the groundwater in Monitoring Well MW-3 fell <br /> from 330 gg/L to 150 gg/L, and TPHg in MW-13 fell from 1,500 gg/L to 390 gg/L, with <br /> a commensurate decline in the concentration of benzene in the water in that well from <br /> 180 gg/L to 120 gg/L, although, further to the north, MTBE, the only analyte of concern <br /> • detected in the sample recovered from Monitoring Well MW-18 on March 30, 2006, rose <br /> to 64 4g/L, compared to 41 gg/L of that analyte on December 20, 2005. <br /> The variations in concentrations of analytes of concern in samples recovered along the <br /> principal plume axis in March 2006 compared to those from the same wells recovered in <br /> December 2005 extend a pattern of seasonal increase and decrease in the concentrations <br /> of fuel hydrocarbons that are related to groundwater flowing into and ebbing away from <br /> t.., the zone of affected soil in response to the seasonal increases in regional agricultural <br /> irrigation that cause temporal concentrations of analytes of concern to reach a seasonal <br /> maximum during the summer months. <br /> 2.5.2 Analytes of Concern in Groundwater around Fringes of Principal Plume <br /> �- Examination of the results of the analyses (see Table 2) of the groundwater samples <br /> recovered from Monitoring Wells MW-2 and MW-5 show that MTBE, the only analyte <br /> F of concern detected in those wells in March 2006, remained at trace concentrations that <br /> �— were essentially unchanged from concentrations measured in samples recovered from <br /> those wells in December 2005. <br /> �~ The sample recovered from Monitoring Well MW-17 on March 30, 2006 contained a <br /> v trace of MTBE at a concentration of 0.70 gg/L. As has been discussed in earlier <br /> `' SJC <br />