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I ., <br /> 1960s before it was banned in 1972. DDT was used extensively throughout the agricultural <br /> fields of the San Joaquin Valley and degradates of DDT are found in virtually all of these soils. <br /> Previous Exposure Assessments made on typical San Joaquin Valley soils suggest an extremely <br /> low probability of adverse health effects from soil DDT/DDD and DDE concentrations (if the <br /> concentrations even exist). <br /> It is important to note that the surface soils currently in-place will undergo significant and <br /> considerable physical and chemical changes during project development. These alterations <br /> include increases in ultraviolet light exposure, moisture content and aeration. Regarding worker r <br /> protection standards during construction: best available technology for dust control during <br /> construction procedures is the wetting of soils. Final concentrations of DDT and its degradates <br /> k in the play areas or garden areas of the new SFR cannot be predicted. It can be reasonably <br /> concluded that the DDT, DDE and DDD concentrations will continue to degrade as reported in <br /> the published environmental fate data. The environmental fate data for DDT and its degradates <br /> DDD and DDE are illustrated below: <br /> DDT. Common name: Agritan, Anofex, Azotox, et al. <br /> Half-lives in the environment: <br /> Air: 17.7 -177 h. <br /> Surface water: 73.9 h for a pond 1 in deep. Degradation half-life of about 10 yr- <br /> average from loss rates determined in Lake Michigan. <br /> Groundwater: 16 d to 31.3 yr. <br /> Sediment: 3 to 5 yr <br /> Soil: 2-15.6 yrs based on observed rates of biodegradation in aerobic soils under <br /> field conditions. Avg. half life of--12 yrs in 3 different soils for -50 ppm in soil. <br /> (conversion of p,p'-DDT to p,p'-DDE). <br /> Environmental Fate Rate Constants or Half-Lives: <br /> Volatilization: Half-life of 3.7 d for water depth of 1 m, from soil w/h-1 of 578 h <br /> Oxidation: Photooxidation half-life of 168-8400 h in water, 17.7-177 h in air <br /> Hydrolysis: Estimated first-order half life of 22 yr <br /> Biodegradation. Aqueous aerobic half-life of 2-15.6 yrs <br /> DDE. Common name: DDE (p,p'-DDE; o,p'-DDE), product of DDT degradation. <br /> Half-lives in the environment: <br /> Air: Atmos. transformation lifetime est. to be < 1 d. <br /> Surface water: Hydrolytic half-life of >120 yr, est. half-life X300 d in lakes. <br /> Groundwater: NIA <br /> Sediment: NIA <br /> Soil: Field half life of 1000 d <br /> Biota: Elimination half-life of 340 d (rainbow trout), 300 d for birds. <br /> Environmental Fate Rate Constants or Half-Lives: <br /> Volatilization: NIA <br /> Oxidation: NIA <br /> Hydrolysis: >120 yr Biodegradation: NIA 4 <br /> Page -4- <br /> Clcr-mery Consulting '� <br />